[1-Dimethyl­silyl-2-phenyl-3-(η(5)-tetra­methyl­cyclo­penta­dien­yl)­prop-1-en-1-yl-κC (1)](η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(III)

The title compound, [Ti(C(10)H(15))(C(20)H(26)Si)], was obtained from the reaction of [Ti{η(5):η(1)-C(5)Me(4)(CH(2))}(η(5)-C(5)Me(5))] with the alkynylsilane PhC(2)SiMe(2)H. The complex crystallizes with two independent mol­ecules in the asymmetric unit, which differ in the conformation of the prope...

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Detalles Bibliográficos
Autores principales: Lamač, Martin, Spannenberg, Anke, Arndt, Perdita, Rosenthal, Uwe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971020/
https://www.ncbi.nlm.nih.gov/pubmed/21578203
http://dx.doi.org/10.1107/S1600536809044845
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author Lamač, Martin
Spannenberg, Anke
Arndt, Perdita
Rosenthal, Uwe
author_facet Lamač, Martin
Spannenberg, Anke
Arndt, Perdita
Rosenthal, Uwe
author_sort Lamač, Martin
collection PubMed
description The title compound, [Ti(C(10)H(15))(C(20)H(26)Si)], was obtained from the reaction of [Ti{η(5):η(1)-C(5)Me(4)(CH(2))}(η(5)-C(5)Me(5))] with the alkynylsilane PhC(2)SiMe(2)H. The complex crystallizes with two independent mol­ecules in the asymmetric unit, which differ in the conformation of the propenyl unit, resulting in their having opposite helicity. No inter­molecular inter­actions or inter­actions involving the Si—H bond are present. The observed geometrical parameters are unexceptional compared to known structures of the same type.
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spelling pubmed-29710202010-12-30 [1-Dimethyl­silyl-2-phenyl-3-(η(5)-tetra­methyl­cyclo­penta­dien­yl)­prop-1-en-1-yl-κC (1)](η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(III) Lamač, Martin Spannenberg, Anke Arndt, Perdita Rosenthal, Uwe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ti(C(10)H(15))(C(20)H(26)Si)], was obtained from the reaction of [Ti{η(5):η(1)-C(5)Me(4)(CH(2))}(η(5)-C(5)Me(5))] with the alkynylsilane PhC(2)SiMe(2)H. The complex crystallizes with two independent mol­ecules in the asymmetric unit, which differ in the conformation of the propenyl unit, resulting in their having opposite helicity. No inter­molecular inter­actions or inter­actions involving the Si—H bond are present. The observed geometrical parameters are unexceptional compared to known structures of the same type. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971020/ /pubmed/21578203 http://dx.doi.org/10.1107/S1600536809044845 Text en © Lamač et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lamač, Martin
Spannenberg, Anke
Arndt, Perdita
Rosenthal, Uwe
[1-Dimethyl­silyl-2-phenyl-3-(η(5)-tetra­methyl­cyclo­penta­dien­yl)­prop-1-en-1-yl-κC (1)](η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(III)
title [1-Dimethyl­silyl-2-phenyl-3-(η(5)-tetra­methyl­cyclo­penta­dien­yl)­prop-1-en-1-yl-κC (1)](η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(III)
title_full [1-Dimethyl­silyl-2-phenyl-3-(η(5)-tetra­methyl­cyclo­penta­dien­yl)­prop-1-en-1-yl-κC (1)](η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(III)
title_fullStr [1-Dimethyl­silyl-2-phenyl-3-(η(5)-tetra­methyl­cyclo­penta­dien­yl)­prop-1-en-1-yl-κC (1)](η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(III)
title_full_unstemmed [1-Dimethyl­silyl-2-phenyl-3-(η(5)-tetra­methyl­cyclo­penta­dien­yl)­prop-1-en-1-yl-κC (1)](η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(III)
title_short [1-Dimethyl­silyl-2-phenyl-3-(η(5)-tetra­methyl­cyclo­penta­dien­yl)­prop-1-en-1-yl-κC (1)](η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(III)
title_sort [1-dimethyl­silyl-2-phenyl-3-(η(5)-tetra­methyl­cyclo­penta­dien­yl)­prop-1-en-1-yl-κc (1)](η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971020/
https://www.ncbi.nlm.nih.gov/pubmed/21578203
http://dx.doi.org/10.1107/S1600536809044845
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AT spannenberganke 1dimethylsilyl2phenyl3ē5tetramethylcyclopentadienylprop1en1ylkc1ē5pentamethylcyclopentadienyltitaniumiii
AT arndtperdita 1dimethylsilyl2phenyl3ē5tetramethylcyclopentadienylprop1en1ylkc1ē5pentamethylcyclopentadienyltitaniumiii
AT rosenthaluwe 1dimethylsilyl2phenyl3ē5tetramethylcyclopentadienylprop1en1ylkc1ē5pentamethylcyclopentadienyltitaniumiii

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