Bis(2-amino-4-chloro­benzoato)triphenyl­anti­mony(V)

The title complex mol­ecule, [Sb(C(6)H(5))(3)(C(7)H(5)ClNO(2))(2)], possesses crystallographically imposed C (2) symmetry. The Sb atom exhibits a trigonal-bipyramidal geometry with the axial positions occupied by the O atoms of two carboxyl­ate groups and the equatorial positions by the C atoms of t...

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Detalles Bibliográficos
Autores principales: Wen, Liyuan, Yin, Handong, Wang, Chuanhua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971026/
https://www.ncbi.nlm.nih.gov/pubmed/21578173
http://dx.doi.org/10.1107/S160053680904358X
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author Wen, Liyuan
Yin, Handong
Wang, Chuanhua
author_facet Wen, Liyuan
Yin, Handong
Wang, Chuanhua
author_sort Wen, Liyuan
collection PubMed
description The title complex mol­ecule, [Sb(C(6)H(5))(3)(C(7)H(5)ClNO(2))(2)], possesses crystallographically imposed C (2) symmetry. The Sb atom exhibits a trigonal-bipyramidal geometry with the axial positions occupied by the O atoms of two carboxyl­ate groups and the equatorial positions by the C atoms of the phenyl groups. Intra­molecular N—H⋯O and C—H⋯O hydrogen bonds occur.
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spelling pubmed-29710262010-12-30 Bis(2-amino-4-chloro­benzoato)triphenyl­anti­mony(V) Wen, Liyuan Yin, Handong Wang, Chuanhua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex mol­ecule, [Sb(C(6)H(5))(3)(C(7)H(5)ClNO(2))(2)], possesses crystallographically imposed C (2) symmetry. The Sb atom exhibits a trigonal-bipyramidal geometry with the axial positions occupied by the O atoms of two carboxyl­ate groups and the equatorial positions by the C atoms of the phenyl groups. Intra­molecular N—H⋯O and C—H⋯O hydrogen bonds occur. International Union of Crystallography 2009-10-28 /pmc/articles/PMC2971026/ /pubmed/21578173 http://dx.doi.org/10.1107/S160053680904358X Text en © Wen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wen, Liyuan
Yin, Handong
Wang, Chuanhua
Bis(2-amino-4-chloro­benzoato)triphenyl­anti­mony(V)
title Bis(2-amino-4-chloro­benzoato)triphenyl­anti­mony(V)
title_full Bis(2-amino-4-chloro­benzoato)triphenyl­anti­mony(V)
title_fullStr Bis(2-amino-4-chloro­benzoato)triphenyl­anti­mony(V)
title_full_unstemmed Bis(2-amino-4-chloro­benzoato)triphenyl­anti­mony(V)
title_short Bis(2-amino-4-chloro­benzoato)triphenyl­anti­mony(V)
title_sort bis(2-amino-4-chloro­benzoato)triphenyl­anti­mony(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971026/
https://www.ncbi.nlm.nih.gov/pubmed/21578173
http://dx.doi.org/10.1107/S160053680904358X
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AT yinhandong bis2amino4chlorobenzoatotriphenylantimonyv
AT wangchuanhua bis2amino4chlorobenzoatotriphenylantimonyv

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