Bis(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))(thio­cyanato-κN)copper(II) chloride

In the title salt, [Cu(NCS)(C(6)H(6)N(4))(2)]Cl, the Cu(II) atom adopts a five-coordinated square-pyramidal geometry consisting of an N atom from a thio­cyanate anion and four N atoms from two chealting biimidazole ligands. The thio­cyanate ligand occupies the axial position and is, like the Cu(II)...

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Detalles Bibliográficos
Autores principales: Ma, Qi, Meng, Shuang-Ming, Feng, Feng, Lu, Li-Ping, Zhu, Miao-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971028/
https://www.ncbi.nlm.nih.gov/pubmed/21578210
http://dx.doi.org/10.1107/S1600536809044717
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author Ma, Qi
Meng, Shuang-Ming
Feng, Feng
Lu, Li-Ping
Zhu, Miao-Li
author_facet Ma, Qi
Meng, Shuang-Ming
Feng, Feng
Lu, Li-Ping
Zhu, Miao-Li
author_sort Ma, Qi
collection PubMed
description In the title salt, [Cu(NCS)(C(6)H(6)N(4))(2)]Cl, the Cu(II) atom adopts a five-coordinated square-pyramidal geometry consisting of an N atom from a thio­cyanate anion and four N atoms from two chealting biimidazole ligands. The thio­cyanate ligand occupies the axial position and is, like the Cu(II) centre, located on a mirror plane. The cation and anion are linked into a linear chain by N—H⋯S and N—H⋯Cl hydrogen bonds.
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spelling pubmed-29710282010-12-30 Bis(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))(thio­cyanato-κN)copper(II) chloride Ma, Qi Meng, Shuang-Ming Feng, Feng Lu, Li-Ping Zhu, Miao-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [Cu(NCS)(C(6)H(6)N(4))(2)]Cl, the Cu(II) atom adopts a five-coordinated square-pyramidal geometry consisting of an N atom from a thio­cyanate anion and four N atoms from two chealting biimidazole ligands. The thio­cyanate ligand occupies the axial position and is, like the Cu(II) centre, located on a mirror plane. The cation and anion are linked into a linear chain by N—H⋯S and N—H⋯Cl hydrogen bonds. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971028/ /pubmed/21578210 http://dx.doi.org/10.1107/S1600536809044717 Text en © Ma et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ma, Qi
Meng, Shuang-Ming
Feng, Feng
Lu, Li-Ping
Zhu, Miao-Li
Bis(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))(thio­cyanato-κN)copper(II) chloride
title Bis(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))(thio­cyanato-κN)copper(II) chloride
title_full Bis(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))(thio­cyanato-κN)copper(II) chloride
title_fullStr Bis(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))(thio­cyanato-κN)copper(II) chloride
title_full_unstemmed Bis(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))(thio­cyanato-κN)copper(II) chloride
title_short Bis(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))(thio­cyanato-κN)copper(II) chloride
title_sort bis(2,2′-bi-1h-imidazole-κ(2) n (3),n (3′))(thio­cyanato-κn)copper(ii) chloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971028/
https://www.ncbi.nlm.nih.gov/pubmed/21578210
http://dx.doi.org/10.1107/S1600536809044717
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