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catena-Poly[[zinc(II)-bis­[μ-1,3-bis­(imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]] dinitrate methanol solvate]

In the title coordination compound, {[Zn(C(14)H(14)N(4))(2)](NO(3))(2)·CH(3)OH}(n), the cationic complex forms a looped chain containing 24-membered M (2) L (2) rings. The ligand adopts two distinct conformations that are alternated in subsequent loops. The Zn(II) ion displays a slightly distorted t...

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Autor principal: Dobrzańska, Liliana
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971030/
https://www.ncbi.nlm.nih.gov/pubmed/21578087
http://dx.doi.org/10.1107/S1600536809040203
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author Dobrzańska, Liliana
author_facet Dobrzańska, Liliana
author_sort Dobrzańska, Liliana
collection PubMed
description In the title coordination compound, {[Zn(C(14)H(14)N(4))(2)](NO(3))(2)·CH(3)OH}(n), the cationic complex forms a looped chain containing 24-membered M (2) L (2) rings. The ligand adopts two distinct conformations that are alternated in subsequent loops. The Zn(II) ion displays a slightly distorted tetra­hedral geometry being coordinated by four N atoms from four 1,3-bis­(imidazol-1-ylmeth­yl)benzene ligands. The nitrate ions and methanol solvent mol­ecules are located between adjacent double-stranded chains and participate in an extensive net of O—H⋯O and C—H⋯O hydrogen bonds. The resulting three-dimensional assembly is further stabilized by π–π inter­actions between benzene rings [centroid–centroid distances = 3.878 (2) and 3.853 (2) Å].
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spelling pubmed-29710302010-12-30 catena-Poly[[zinc(II)-bis­[μ-1,3-bis­(imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]] dinitrate methanol solvate] Dobrzańska, Liliana Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination compound, {[Zn(C(14)H(14)N(4))(2)](NO(3))(2)·CH(3)OH}(n), the cationic complex forms a looped chain containing 24-membered M (2) L (2) rings. The ligand adopts two distinct conformations that are alternated in subsequent loops. The Zn(II) ion displays a slightly distorted tetra­hedral geometry being coordinated by four N atoms from four 1,3-bis­(imidazol-1-ylmeth­yl)benzene ligands. The nitrate ions and methanol solvent mol­ecules are located between adjacent double-stranded chains and participate in an extensive net of O—H⋯O and C—H⋯O hydrogen bonds. The resulting three-dimensional assembly is further stabilized by π–π inter­actions between benzene rings [centroid–centroid distances = 3.878 (2) and 3.853 (2) Å]. International Union of Crystallography 2009-10-10 /pmc/articles/PMC2971030/ /pubmed/21578087 http://dx.doi.org/10.1107/S1600536809040203 Text en © Liliana Dobrzańska 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dobrzańska, Liliana
catena-Poly[[zinc(II)-bis­[μ-1,3-bis­(imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]] dinitrate methanol solvate]
title catena-Poly[[zinc(II)-bis­[μ-1,3-bis­(imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]] dinitrate methanol solvate]
title_full catena-Poly[[zinc(II)-bis­[μ-1,3-bis­(imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]] dinitrate methanol solvate]
title_fullStr catena-Poly[[zinc(II)-bis­[μ-1,3-bis­(imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]] dinitrate methanol solvate]
title_full_unstemmed catena-Poly[[zinc(II)-bis­[μ-1,3-bis­(imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]] dinitrate methanol solvate]
title_short catena-Poly[[zinc(II)-bis­[μ-1,3-bis­(imidazol-1-ylmeth­yl)benzene-κ(2) N (3):N (3′)]] dinitrate methanol solvate]
title_sort catena-poly[[zinc(ii)-bis­[μ-1,3-bis­(imidazol-1-ylmeth­yl)benzene-κ(2) n (3):n (3′)]] dinitrate methanol solvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971030/
https://www.ncbi.nlm.nih.gov/pubmed/21578087
http://dx.doi.org/10.1107/S1600536809040203
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