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catena-Poly[[zinc(II)-bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ(2) N (3):N (3′)]] dinitrate methanol solvate]
In the title coordination compound, {[Zn(C(14)H(14)N(4))(2)](NO(3))(2)·CH(3)OH}(n), the cationic complex forms a looped chain containing 24-membered M (2) L (2) rings. The ligand adopts two distinct conformations that are alternated in subsequent loops. The Zn(II) ion displays a slightly distorted t...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971030/ https://www.ncbi.nlm.nih.gov/pubmed/21578087 http://dx.doi.org/10.1107/S1600536809040203 |
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author | Dobrzańska, Liliana |
author_facet | Dobrzańska, Liliana |
author_sort | Dobrzańska, Liliana |
collection | PubMed |
description | In the title coordination compound, {[Zn(C(14)H(14)N(4))(2)](NO(3))(2)·CH(3)OH}(n), the cationic complex forms a looped chain containing 24-membered M (2) L (2) rings. The ligand adopts two distinct conformations that are alternated in subsequent loops. The Zn(II) ion displays a slightly distorted tetrahedral geometry being coordinated by four N atoms from four 1,3-bis(imidazol-1-ylmethyl)benzene ligands. The nitrate ions and methanol solvent molecules are located between adjacent double-stranded chains and participate in an extensive net of O—H⋯O and C—H⋯O hydrogen bonds. The resulting three-dimensional assembly is further stabilized by π–π interactions between benzene rings [centroid–centroid distances = 3.878 (2) and 3.853 (2) Å]. |
format | Text |
id | pubmed-2971030 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29710302010-12-30 catena-Poly[[zinc(II)-bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ(2) N (3):N (3′)]] dinitrate methanol solvate] Dobrzańska, Liliana Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination compound, {[Zn(C(14)H(14)N(4))(2)](NO(3))(2)·CH(3)OH}(n), the cationic complex forms a looped chain containing 24-membered M (2) L (2) rings. The ligand adopts two distinct conformations that are alternated in subsequent loops. The Zn(II) ion displays a slightly distorted tetrahedral geometry being coordinated by four N atoms from four 1,3-bis(imidazol-1-ylmethyl)benzene ligands. The nitrate ions and methanol solvent molecules are located between adjacent double-stranded chains and participate in an extensive net of O—H⋯O and C—H⋯O hydrogen bonds. The resulting three-dimensional assembly is further stabilized by π–π interactions between benzene rings [centroid–centroid distances = 3.878 (2) and 3.853 (2) Å]. International Union of Crystallography 2009-10-10 /pmc/articles/PMC2971030/ /pubmed/21578087 http://dx.doi.org/10.1107/S1600536809040203 Text en © Liliana Dobrzańska 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Dobrzańska, Liliana catena-Poly[[zinc(II)-bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ(2) N (3):N (3′)]] dinitrate methanol solvate] |
title |
catena-Poly[[zinc(II)-bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]] dinitrate methanol solvate] |
title_full |
catena-Poly[[zinc(II)-bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]] dinitrate methanol solvate] |
title_fullStr |
catena-Poly[[zinc(II)-bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]] dinitrate methanol solvate] |
title_full_unstemmed |
catena-Poly[[zinc(II)-bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]] dinitrate methanol solvate] |
title_short |
catena-Poly[[zinc(II)-bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]] dinitrate methanol solvate] |
title_sort | catena-poly[[zinc(ii)-bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ(2)
n
(3):n
(3′)]] dinitrate methanol solvate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971030/ https://www.ncbi.nlm.nih.gov/pubmed/21578087 http://dx.doi.org/10.1107/S1600536809040203 |
work_keys_str_mv | AT dobrzanskaliliana catenapolyzinciibism13bisimidazol1ylmethylbenzenek2n3n3dinitratemethanolsolvate |