Dipotassium samarium(III) molybdate(VI) phosphate(V), K(2)Sm(MoO(4))(PO(4))

The title compound, K(2)Sm(MoO(4))(PO(4)), has been prepared under atmospheric conditions using a high temperature solution growth (HTSG) method. The structure of K(2)Sm(MoO(4))(PO(4)) is isotypic with other A (2) M(MoO(4))(PO(4)) compounds, where A = Na or K, and M = trivalent rare earth cation. It...

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Detalles Bibliográficos
Autores principales: Zhao, Dan, Li, Feifei, Cheng, Wendan, Zhang, Hao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971031/
https://www.ncbi.nlm.nih.gov/pubmed/21578036
http://dx.doi.org/10.1107/S1600536809041622
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author Zhao, Dan
Li, Feifei
Cheng, Wendan
Zhang, Hao
author_facet Zhao, Dan
Li, Feifei
Cheng, Wendan
Zhang, Hao
author_sort Zhao, Dan
collection PubMed
description The title compound, K(2)Sm(MoO(4))(PO(4)), has been prepared under atmospheric conditions using a high temperature solution growth (HTSG) method. The structure of K(2)Sm(MoO(4))(PO(4)) is isotypic with other A (2) M(MoO(4))(PO(4)) compounds, where A = Na or K, and M = trivalent rare earth cation. It can be described as being built up from two-dimensional anionic layers with composition [Sm(MoO(4))(PO(4))](2−) that are stacked along the c axis and are inter­connected by K(+) cations which are in an eightfold coordination by O atoms. The SmO(8), MoO(4) and PO(4) polyhedra exhibit 2 symmetry.
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spelling pubmed-29710312010-12-30 Dipotassium samarium(III) molybdate(VI) phosphate(V), K(2)Sm(MoO(4))(PO(4)) Zhao, Dan Li, Feifei Cheng, Wendan Zhang, Hao Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, K(2)Sm(MoO(4))(PO(4)), has been prepared under atmospheric conditions using a high temperature solution growth (HTSG) method. The structure of K(2)Sm(MoO(4))(PO(4)) is isotypic with other A (2) M(MoO(4))(PO(4)) compounds, where A = Na or K, and M = trivalent rare earth cation. It can be described as being built up from two-dimensional anionic layers with composition [Sm(MoO(4))(PO(4))](2−) that are stacked along the c axis and are inter­connected by K(+) cations which are in an eightfold coordination by O atoms. The SmO(8), MoO(4) and PO(4) polyhedra exhibit 2 symmetry. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971031/ /pubmed/21578036 http://dx.doi.org/10.1107/S1600536809041622 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Zhao, Dan
Li, Feifei
Cheng, Wendan
Zhang, Hao
Dipotassium samarium(III) molybdate(VI) phosphate(V), K(2)Sm(MoO(4))(PO(4))
title Dipotassium samarium(III) molybdate(VI) phosphate(V), K(2)Sm(MoO(4))(PO(4))
title_full Dipotassium samarium(III) molybdate(VI) phosphate(V), K(2)Sm(MoO(4))(PO(4))
title_fullStr Dipotassium samarium(III) molybdate(VI) phosphate(V), K(2)Sm(MoO(4))(PO(4))
title_full_unstemmed Dipotassium samarium(III) molybdate(VI) phosphate(V), K(2)Sm(MoO(4))(PO(4))
title_short Dipotassium samarium(III) molybdate(VI) phosphate(V), K(2)Sm(MoO(4))(PO(4))
title_sort dipotassium samarium(iii) molybdate(vi) phosphate(v), k(2)sm(moo(4))(po(4))
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971031/
https://www.ncbi.nlm.nih.gov/pubmed/21578036
http://dx.doi.org/10.1107/S1600536809041622
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