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2-[N-(2,4-Difluorophenyl)carbamoyl]-3,4,5,6-tetrafluorobenzoic acid
The title compound, C(14)H(5)F(6)NO(3), was synthesized by condensation of tetrafluorophthalic anhydride and 2,4-difluoroaniline. It was then recrystallized from hexane to give a nonmerohedral twin with two crystallographically unique molecules in the asymmetric unit. The refined twin fraction i...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971039/ https://www.ncbi.nlm.nih.gov/pubmed/21578258 http://dx.doi.org/10.1107/S1600536809038306 |
Sumario: | The title compound, C(14)H(5)F(6)NO(3), was synthesized by condensation of tetrafluorophthalic anhydride and 2,4-difluoroaniline. It was then recrystallized from hexane to give a nonmerohedral twin with two crystallographically unique molecules in the asymmetric unit. The refined twin fraction is 0.460 (3). Torsional differences between the aryl rings and the central amide group account for the presence of two unique molecules. The compound packs as double tapes formed by O—H⋯O and N—H⋯O hydrogen-bonding interactions between each unique molecule and its symmetry equivalents. |
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