2-[(N-Benzyl-4-methyl­benzene­sul­fon­amido)meth­yl]pyridinium nitrate

In the title compound, C(20)H(21)N(2)O(2)S(+)·NO(3) (−), the dihedral angle between the pyridinium and phenyl rings is 81.77 (19)°, that between the pyridinium and tolyl rings is 1.36 (18)°, and that between the phenyl and tolyl rings is 82.69 (19)°. In the crystal, the components are linked by stro...

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Detalles Bibliográficos
Autores principales: Li, Jiang-Sheng, Simpson, Jim
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971041/
https://www.ncbi.nlm.nih.gov/pubmed/21578405
http://dx.doi.org/10.1107/S1600536809042330
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author Li, Jiang-Sheng
Simpson, Jim
author_facet Li, Jiang-Sheng
Simpson, Jim
author_sort Li, Jiang-Sheng
collection PubMed
description In the title compound, C(20)H(21)N(2)O(2)S(+)·NO(3) (−), the dihedral angle between the pyridinium and phenyl rings is 81.77 (19)°, that between the pyridinium and tolyl rings is 1.36 (18)°, and that between the phenyl and tolyl rings is 82.69 (19)°. In the crystal, the components are linked by strong charge-assisted bifurcated N(+)—H⋯(O,O) hydrogen bonds and the packing is consolidated by numerous weak C—H⋯O bonds and π–π stacking inter­actions [for the latter, centroid–centroid separation = 3.868 (2) Å].
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spelling pubmed-29710412010-12-30 2-[(N-Benzyl-4-methyl­benzene­sul­fon­amido)meth­yl]pyridinium nitrate Li, Jiang-Sheng Simpson, Jim Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(21)N(2)O(2)S(+)·NO(3) (−), the dihedral angle between the pyridinium and phenyl rings is 81.77 (19)°, that between the pyridinium and tolyl rings is 1.36 (18)°, and that between the phenyl and tolyl rings is 82.69 (19)°. In the crystal, the components are linked by strong charge-assisted bifurcated N(+)—H⋯(O,O) hydrogen bonds and the packing is consolidated by numerous weak C—H⋯O bonds and π–π stacking inter­actions [for the latter, centroid–centroid separation = 3.868 (2) Å]. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971041/ /pubmed/21578405 http://dx.doi.org/10.1107/S1600536809042330 Text en © Li and Simpson 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Jiang-Sheng
Simpson, Jim
2-[(N-Benzyl-4-methyl­benzene­sul­fon­amido)meth­yl]pyridinium nitrate
title 2-[(N-Benzyl-4-methyl­benzene­sul­fon­amido)meth­yl]pyridinium nitrate
title_full 2-[(N-Benzyl-4-methyl­benzene­sul­fon­amido)meth­yl]pyridinium nitrate
title_fullStr 2-[(N-Benzyl-4-methyl­benzene­sul­fon­amido)meth­yl]pyridinium nitrate
title_full_unstemmed 2-[(N-Benzyl-4-methyl­benzene­sul­fon­amido)meth­yl]pyridinium nitrate
title_short 2-[(N-Benzyl-4-methyl­benzene­sul­fon­amido)meth­yl]pyridinium nitrate
title_sort 2-[(n-benzyl-4-methyl­benzene­sul­fon­amido)meth­yl]pyridinium nitrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971041/
https://www.ncbi.nlm.nih.gov/pubmed/21578405
http://dx.doi.org/10.1107/S1600536809042330
work_keys_str_mv AT lijiangsheng 2nbenzyl4methylbenzenesulfonamidomethylpyridiniumnitrate
AT simpsonjim 2nbenzyl4methylbenzenesulfonamidomethylpyridiniumnitrate

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