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1,5-Bis[(E)-1-(2-hydroxy­phen­yl)ethyl­idene]carbonohydrazide dimethyl sulfoxide solvate

The title dimethyl sulfoxide (DMSO) solvate, C(17)H(18)N(4)O(3)·C(2)H(6)OS, shows the disubstituted urea derivative to adopt an almost planar geometry (r.m.s. deviation for non-H atoms = 0.132 Å); the mol­ecule has non-crystallographic twofold mol­ecular symmetry. This conformation is stabilized by...

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Detalles Bibliográficos
Autores principales: Zukerman-Schpector, Julio, Affan, Md. Abu, Foo, Siong Wan, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971043/
https://www.ncbi.nlm.nih.gov/pubmed/21578524
http://dx.doi.org/10.1107/S1600536809044985
Descripción
Sumario:The title dimethyl sulfoxide (DMSO) solvate, C(17)H(18)N(4)O(3)·C(2)H(6)OS, shows the disubstituted urea derivative to adopt an almost planar geometry (r.m.s. deviation for non-H atoms = 0.132 Å); the mol­ecule has non-crystallographic twofold mol­ecular symmetry. This conformation is stabilized by two intra­molecular O—H⋯N hydrogen bonds. The components of the crystal are connected by N—H⋯O hydrogen bonds, whereby both amine H atoms are connected to a DMSO O atom, and C—H⋯O contacts involving the DMSO H and urea carbonyl atoms, forming a supra­molecular chain along the c axis. The chains associate via C—H⋯π inter­actions.