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1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]carbonohydrazide dimethyl sulfoxide solvate
The title dimethyl sulfoxide (DMSO) solvate, C(17)H(18)N(4)O(3)·C(2)H(6)OS, shows the disubstituted urea derivative to adopt an almost planar geometry (r.m.s. deviation for non-H atoms = 0.132 Å); the molecule has non-crystallographic twofold molecular symmetry. This conformation is stabilized by...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971043/ https://www.ncbi.nlm.nih.gov/pubmed/21578524 http://dx.doi.org/10.1107/S1600536809044985 |
Sumario: | The title dimethyl sulfoxide (DMSO) solvate, C(17)H(18)N(4)O(3)·C(2)H(6)OS, shows the disubstituted urea derivative to adopt an almost planar geometry (r.m.s. deviation for non-H atoms = 0.132 Å); the molecule has non-crystallographic twofold molecular symmetry. This conformation is stabilized by two intramolecular O—H⋯N hydrogen bonds. The components of the crystal are connected by N—H⋯O hydrogen bonds, whereby both amine H atoms are connected to a DMSO O atom, and C—H⋯O contacts involving the DMSO H and urea carbonyl atoms, forming a supramolecular chain along the c axis. The chains associate via C—H⋯π interactions. |
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