1,5-Bis[(E)-1-(2-hydroxy­phen­yl)ethyl­idene]carbonohydrazide dimethyl sulfoxide solvate

The title dimethyl sulfoxide (DMSO) solvate, C(17)H(18)N(4)O(3)·C(2)H(6)OS, shows the disubstituted urea derivative to adopt an almost planar geometry (r.m.s. deviation for non-H atoms = 0.132 Å); the mol­ecule has non-crystallographic twofold mol­ecular symmetry. This conformation is stabilized by...

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Autores principales: Zukerman-Schpector, Julio, Affan, Md. Abu, Foo, Siong Wan, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971043/
https://www.ncbi.nlm.nih.gov/pubmed/21578524
http://dx.doi.org/10.1107/S1600536809044985
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author Zukerman-Schpector, Julio
Affan, Md. Abu
Foo, Siong Wan
Tiekink, Edward R. T.
author_facet Zukerman-Schpector, Julio
Affan, Md. Abu
Foo, Siong Wan
Tiekink, Edward R. T.
author_sort Zukerman-Schpector, Julio
collection PubMed
description The title dimethyl sulfoxide (DMSO) solvate, C(17)H(18)N(4)O(3)·C(2)H(6)OS, shows the disubstituted urea derivative to adopt an almost planar geometry (r.m.s. deviation for non-H atoms = 0.132 Å); the mol­ecule has non-crystallographic twofold mol­ecular symmetry. This conformation is stabilized by two intra­molecular O—H⋯N hydrogen bonds. The components of the crystal are connected by N—H⋯O hydrogen bonds, whereby both amine H atoms are connected to a DMSO O atom, and C—H⋯O contacts involving the DMSO H and urea carbonyl atoms, forming a supra­molecular chain along the c axis. The chains associate via C—H⋯π inter­actions.
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spelling pubmed-29710432010-12-30 1,5-Bis[(E)-1-(2-hydroxy­phen­yl)ethyl­idene]carbonohydrazide dimethyl sulfoxide solvate Zukerman-Schpector, Julio Affan, Md. Abu Foo, Siong Wan Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title dimethyl sulfoxide (DMSO) solvate, C(17)H(18)N(4)O(3)·C(2)H(6)OS, shows the disubstituted urea derivative to adopt an almost planar geometry (r.m.s. deviation for non-H atoms = 0.132 Å); the mol­ecule has non-crystallographic twofold mol­ecular symmetry. This conformation is stabilized by two intra­molecular O—H⋯N hydrogen bonds. The components of the crystal are connected by N—H⋯O hydrogen bonds, whereby both amine H atoms are connected to a DMSO O atom, and C—H⋯O contacts involving the DMSO H and urea carbonyl atoms, forming a supra­molecular chain along the c axis. The chains associate via C—H⋯π inter­actions. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971043/ /pubmed/21578524 http://dx.doi.org/10.1107/S1600536809044985 Text en © Zukerman-Schpector et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zukerman-Schpector, Julio
Affan, Md. Abu
Foo, Siong Wan
Tiekink, Edward R. T.
1,5-Bis[(E)-1-(2-hydroxy­phen­yl)ethyl­idene]carbonohydrazide dimethyl sulfoxide solvate
title 1,5-Bis[(E)-1-(2-hydroxy­phen­yl)ethyl­idene]carbonohydrazide dimethyl sulfoxide solvate
title_full 1,5-Bis[(E)-1-(2-hydroxy­phen­yl)ethyl­idene]carbonohydrazide dimethyl sulfoxide solvate
title_fullStr 1,5-Bis[(E)-1-(2-hydroxy­phen­yl)ethyl­idene]carbonohydrazide dimethyl sulfoxide solvate
title_full_unstemmed 1,5-Bis[(E)-1-(2-hydroxy­phen­yl)ethyl­idene]carbonohydrazide dimethyl sulfoxide solvate
title_short 1,5-Bis[(E)-1-(2-hydroxy­phen­yl)ethyl­idene]carbonohydrazide dimethyl sulfoxide solvate
title_sort 1,5-bis[(e)-1-(2-hydroxy­phen­yl)ethyl­idene]carbonohydrazide dimethyl sulfoxide solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971043/
https://www.ncbi.nlm.nih.gov/pubmed/21578524
http://dx.doi.org/10.1107/S1600536809044985
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