cis-Diaqua­bis(2,2′,2′′-tripyridylamine)zinc(II) bis­(perchlorate)

In the title compound, [Zn(2,2′,2′′-tpa)(2)(H(2)O)(2)](ClO(4))(2) (2,2′,2′′-tpa is 2,2′,2′′-tripyridylamine, C(15)H(12)N(4)), the Zn center lies on a twofold axis and is coordinated octa­hedrally by two water mol­ecules and two bidentate 2,2′,2′′-tpa ligands. The perchlorate anions are linked to the...

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Detalles Bibliográficos
Autores principales: Wang, Shi, Ding, Xuehua, He, Wenrui, Huang, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971047/
https://www.ncbi.nlm.nih.gov/pubmed/21578160
http://dx.doi.org/10.1107/S1600536809042688
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author Wang, Shi
Ding, Xuehua
He, Wenrui
Huang, Wei
author_facet Wang, Shi
Ding, Xuehua
He, Wenrui
Huang, Wei
author_sort Wang, Shi
collection PubMed
description In the title compound, [Zn(2,2′,2′′-tpa)(2)(H(2)O)(2)](ClO(4))(2) (2,2′,2′′-tpa is 2,2′,2′′-tripyridylamine, C(15)H(12)N(4)), the Zn center lies on a twofold axis and is coordinated octa­hedrally by two water mol­ecules and two bidentate 2,2′,2′′-tpa ligands. The perchlorate anions are linked to the coordinated water mol­ecules in the complex cations via O—H⋯O hydrogen bonds.
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spelling pubmed-29710472010-12-30 cis-Diaqua­bis(2,2′,2′′-tripyridylamine)zinc(II) bis­(perchlorate) Wang, Shi Ding, Xuehua He, Wenrui Huang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(2,2′,2′′-tpa)(2)(H(2)O)(2)](ClO(4))(2) (2,2′,2′′-tpa is 2,2′,2′′-tripyridylamine, C(15)H(12)N(4)), the Zn center lies on a twofold axis and is coordinated octa­hedrally by two water mol­ecules and two bidentate 2,2′,2′′-tpa ligands. The perchlorate anions are linked to the coordinated water mol­ecules in the complex cations via O—H⋯O hydrogen bonds. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971047/ /pubmed/21578160 http://dx.doi.org/10.1107/S1600536809042688 Text en © Wang* et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Shi
Ding, Xuehua
He, Wenrui
Huang, Wei
cis-Diaqua­bis(2,2′,2′′-tripyridylamine)zinc(II) bis­(perchlorate)
title cis-Diaqua­bis(2,2′,2′′-tripyridylamine)zinc(II) bis­(perchlorate)
title_full cis-Diaqua­bis(2,2′,2′′-tripyridylamine)zinc(II) bis­(perchlorate)
title_fullStr cis-Diaqua­bis(2,2′,2′′-tripyridylamine)zinc(II) bis­(perchlorate)
title_full_unstemmed cis-Diaqua­bis(2,2′,2′′-tripyridylamine)zinc(II) bis­(perchlorate)
title_short cis-Diaqua­bis(2,2′,2′′-tripyridylamine)zinc(II) bis­(perchlorate)
title_sort cis-diaqua­bis(2,2′,2′′-tripyridylamine)zinc(ii) bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971047/
https://www.ncbi.nlm.nih.gov/pubmed/21578160
http://dx.doi.org/10.1107/S1600536809042688
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