Carbon­yl[4-(2,3-dimethyl­phenyl­amino)pent-3-en-2-onato-κ(2) N,O](triphenyl­phosphine-κP)rhodium(I)

In the title compound, [Rh(C(13)H(16)NO)(C(18)H(15)P)(CO)], the coordination geometry of the Rh(I) atom is square-planar, formed by the coordinating N and O atoms of the bidentate enaminoketonate ligand, one C atom from the carbonyl group and a P atom from triphenyl­phosphine. The complex displays a...

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Detalles Bibliográficos
Autores principales: Venter, Gertruida J. S., Steyl, Gideon, Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971050/
https://www.ncbi.nlm.nih.gov/pubmed/21578084
http://dx.doi.org/10.1107/S1600536809039816
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author Venter, Gertruida J. S.
Steyl, Gideon
Roodt, Andreas
author_facet Venter, Gertruida J. S.
Steyl, Gideon
Roodt, Andreas
author_sort Venter, Gertruida J. S.
collection PubMed
description In the title compound, [Rh(C(13)H(16)NO)(C(18)H(15)P)(CO)], the coordination geometry of the Rh(I) atom is square-planar, formed by the coordinating N and O atoms of the bidentate enaminoketonate ligand, one C atom from the carbonyl group and a P atom from triphenyl­phosphine. The complex displays a 0.591 (3):0.409 (3) ratio disorder of the phenyl unit of the monoanionic N,O-bidentate ligand. Intra­molecular hydrogen bonding is observed between a C—H group of the triphenyl­phosphine unit and the O atom of the enamino­ketonate ligand.
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spelling pubmed-29710502010-12-30 Carbon­yl[4-(2,3-dimethyl­phenyl­amino)pent-3-en-2-onato-κ(2) N,O](triphenyl­phosphine-κP)rhodium(I) Venter, Gertruida J. S. Steyl, Gideon Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Rh(C(13)H(16)NO)(C(18)H(15)P)(CO)], the coordination geometry of the Rh(I) atom is square-planar, formed by the coordinating N and O atoms of the bidentate enaminoketonate ligand, one C atom from the carbonyl group and a P atom from triphenyl­phosphine. The complex displays a 0.591 (3):0.409 (3) ratio disorder of the phenyl unit of the monoanionic N,O-bidentate ligand. Intra­molecular hydrogen bonding is observed between a C—H group of the triphenyl­phosphine unit and the O atom of the enamino­ketonate ligand. International Union of Crystallography 2009-10-07 /pmc/articles/PMC2971050/ /pubmed/21578084 http://dx.doi.org/10.1107/S1600536809039816 Text en © Venter et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Venter, Gertruida J. S.
Steyl, Gideon
Roodt, Andreas
Carbon­yl[4-(2,3-dimethyl­phenyl­amino)pent-3-en-2-onato-κ(2) N,O](triphenyl­phosphine-κP)rhodium(I)
title Carbon­yl[4-(2,3-dimethyl­phenyl­amino)pent-3-en-2-onato-κ(2) N,O](triphenyl­phosphine-κP)rhodium(I)
title_full Carbon­yl[4-(2,3-dimethyl­phenyl­amino)pent-3-en-2-onato-κ(2) N,O](triphenyl­phosphine-κP)rhodium(I)
title_fullStr Carbon­yl[4-(2,3-dimethyl­phenyl­amino)pent-3-en-2-onato-κ(2) N,O](triphenyl­phosphine-κP)rhodium(I)
title_full_unstemmed Carbon­yl[4-(2,3-dimethyl­phenyl­amino)pent-3-en-2-onato-κ(2) N,O](triphenyl­phosphine-κP)rhodium(I)
title_short Carbon­yl[4-(2,3-dimethyl­phenyl­amino)pent-3-en-2-onato-κ(2) N,O](triphenyl­phosphine-κP)rhodium(I)
title_sort carbon­yl[4-(2,3-dimethyl­phenyl­amino)pent-3-en-2-onato-κ(2) n,o](triphenyl­phosphine-κp)rhodium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971050/
https://www.ncbi.nlm.nih.gov/pubmed/21578084
http://dx.doi.org/10.1107/S1600536809039816
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AT roodtandreas carbonyl423dimethylphenylaminopent3en2onatok2notriphenylphosphinekprhodiumi

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