Bis(μ-6-hydroxy­naphthalene-1-carboxyl­ato)bis­[(6-hydroxy­naphthalene-1-car­box­yl­ato)(1,10-phenanthroline)cadmium(II)] tetra­hydrate

The title complex, [Cd(2)(C(11)H(7)O(3))(4)(C(12)H(8)N(2))(2)]·4H(2)O, has a centrosymmetric binuclear structure in which two Cd(II) atoms are both six-coordinated and bridged by 6-hydroxy­naphthalene-1-carboxyl­ate ligands, with a Cd⋯Cd separation of 3.671 (1) Å. The remaining coordination sites ar...

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Detalles Bibliográficos
Autores principales: Liu, Chun-Sen, Hu, Min, Guo, Liang-Qi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971052/
https://www.ncbi.nlm.nih.gov/pubmed/21578166
http://dx.doi.org/10.1107/S1600536809043475
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author Liu, Chun-Sen
Hu, Min
Guo, Liang-Qi
author_facet Liu, Chun-Sen
Hu, Min
Guo, Liang-Qi
author_sort Liu, Chun-Sen
collection PubMed
description The title complex, [Cd(2)(C(11)H(7)O(3))(4)(C(12)H(8)N(2))(2)]·4H(2)O, has a centrosymmetric binuclear structure in which two Cd(II) atoms are both six-coordinated and bridged by 6-hydroxy­naphthalene-1-carboxyl­ate ligands, with a Cd⋯Cd separation of 3.671 (1) Å. The remaining coordination sites are occupied by two N atoms of a 1,10-phenanthroline ligand and two O atoms of a 6-hydroxy­naphthalene-1-carboxyl­ate ligand. The crystal packing is stabilized by O—H⋯O hydrogen-bonding inter­actions.
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spelling pubmed-29710522010-12-30 Bis(μ-6-hydroxy­naphthalene-1-carboxyl­ato)bis­[(6-hydroxy­naphthalene-1-car­box­yl­ato)(1,10-phenanthroline)cadmium(II)] tetra­hydrate Liu, Chun-Sen Hu, Min Guo, Liang-Qi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cd(2)(C(11)H(7)O(3))(4)(C(12)H(8)N(2))(2)]·4H(2)O, has a centrosymmetric binuclear structure in which two Cd(II) atoms are both six-coordinated and bridged by 6-hydroxy­naphthalene-1-carboxyl­ate ligands, with a Cd⋯Cd separation of 3.671 (1) Å. The remaining coordination sites are occupied by two N atoms of a 1,10-phenanthroline ligand and two O atoms of a 6-hydroxy­naphthalene-1-carboxyl­ate ligand. The crystal packing is stabilized by O—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2009-10-28 /pmc/articles/PMC2971052/ /pubmed/21578166 http://dx.doi.org/10.1107/S1600536809043475 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Chun-Sen
Hu, Min
Guo, Liang-Qi
Bis(μ-6-hydroxy­naphthalene-1-carboxyl­ato)bis­[(6-hydroxy­naphthalene-1-car­box­yl­ato)(1,10-phenanthroline)cadmium(II)] tetra­hydrate
title Bis(μ-6-hydroxy­naphthalene-1-carboxyl­ato)bis­[(6-hydroxy­naphthalene-1-car­box­yl­ato)(1,10-phenanthroline)cadmium(II)] tetra­hydrate
title_full Bis(μ-6-hydroxy­naphthalene-1-carboxyl­ato)bis­[(6-hydroxy­naphthalene-1-car­box­yl­ato)(1,10-phenanthroline)cadmium(II)] tetra­hydrate
title_fullStr Bis(μ-6-hydroxy­naphthalene-1-carboxyl­ato)bis­[(6-hydroxy­naphthalene-1-car­box­yl­ato)(1,10-phenanthroline)cadmium(II)] tetra­hydrate
title_full_unstemmed Bis(μ-6-hydroxy­naphthalene-1-carboxyl­ato)bis­[(6-hydroxy­naphthalene-1-car­box­yl­ato)(1,10-phenanthroline)cadmium(II)] tetra­hydrate
title_short Bis(μ-6-hydroxy­naphthalene-1-carboxyl­ato)bis­[(6-hydroxy­naphthalene-1-car­box­yl­ato)(1,10-phenanthroline)cadmium(II)] tetra­hydrate
title_sort bis(μ-6-hydroxy­naphthalene-1-carboxyl­ato)bis­[(6-hydroxy­naphthalene-1-car­box­yl­ato)(1,10-phenanthroline)cadmium(ii)] tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971052/
https://www.ncbi.nlm.nih.gov/pubmed/21578166
http://dx.doi.org/10.1107/S1600536809043475
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