Octa­butyl­bis{(E)-2-[4-(2-hydroxy­benzyl­ideneamino)phen­yl]acetato}di-μ(2)-methoxo-di-μ(3)-oxido-tetra­tin(IV)

The title compound, [Sn(4)(C(4)H(9))(8)(C(15)H(12)NO(3))(2)(CH(3)O)(2)O(2)], is a centrosymmetric dimer and displays a ladder type structural motif. There are four Sn(IV) centres which can be divided into two sorts, viz. two endocyclic and two exocyclic. The endo- and exocyclic Sn(IV) centres are li...

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Detalles Bibliográficos
Autores principales: Li, Wenkuan, Yin, Handong, Wen, Liyuan, Wang, Daqi, Fan, Weidong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971054/
https://www.ncbi.nlm.nih.gov/pubmed/21578042
http://dx.doi.org/10.1107/S1600536809038938
Descripción
Sumario:The title compound, [Sn(4)(C(4)H(9))(8)(C(15)H(12)NO(3))(2)(CH(3)O)(2)O(2)], is a centrosymmetric dimer and displays a ladder type structural motif. There are four Sn(IV) centres which can be divided into two sorts, viz. two endocyclic and two exocyclic. The endo- and exocyclic Sn(IV) centres are linked by bidentate deprotonated methanol and μ(3)-O atoms. Each exocyclic Sn(IV) centre is also coordinated by a monodentate 2-[4-(2-hydroxy­benzyl­idene­amino)phen­yl]acetate ligand. Parts of the butyl groups were found to be disordered over two sets of sites.

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