Octa­butyl­bis{(E)-2-[4-(2-hydroxy­benzyl­ideneamino)phen­yl]acetato}di-μ(2)-methoxo-di-μ(3)-oxido-tetra­tin(IV)

The title compound, [Sn(4)(C(4)H(9))(8)(C(15)H(12)NO(3))(2)(CH(3)O)(2)O(2)], is a centrosymmetric dimer and displays a ladder type structural motif. There are four Sn(IV) centres which can be divided into two sorts, viz. two endocyclic and two exocyclic. The endo- and exocyclic Sn(IV) centres are li...

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Detalles Bibliográficos
Autores principales: Li, Wenkuan, Yin, Handong, Wen, Liyuan, Wang, Daqi, Fan, Weidong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971054/
https://www.ncbi.nlm.nih.gov/pubmed/21578042
http://dx.doi.org/10.1107/S1600536809038938
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author Li, Wenkuan
Yin, Handong
Wen, Liyuan
Wang, Daqi
Fan, Weidong
author_facet Li, Wenkuan
Yin, Handong
Wen, Liyuan
Wang, Daqi
Fan, Weidong
author_sort Li, Wenkuan
collection PubMed
description The title compound, [Sn(4)(C(4)H(9))(8)(C(15)H(12)NO(3))(2)(CH(3)O)(2)O(2)], is a centrosymmetric dimer and displays a ladder type structural motif. There are four Sn(IV) centres which can be divided into two sorts, viz. two endocyclic and two exocyclic. The endo- and exocyclic Sn(IV) centres are linked by bidentate deprotonated methanol and μ(3)-O atoms. Each exocyclic Sn(IV) centre is also coordinated by a monodentate 2-[4-(2-hydroxy­benzyl­idene­amino)phen­yl]acetate ligand. Parts of the butyl groups were found to be disordered over two sets of sites.
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spelling pubmed-29710542010-12-30 Octa­butyl­bis{(E)-2-[4-(2-hydroxy­benzyl­ideneamino)phen­yl]acetato}di-μ(2)-methoxo-di-μ(3)-oxido-tetra­tin(IV) Li, Wenkuan Yin, Handong Wen, Liyuan Wang, Daqi Fan, Weidong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(4)(C(4)H(9))(8)(C(15)H(12)NO(3))(2)(CH(3)O)(2)O(2)], is a centrosymmetric dimer and displays a ladder type structural motif. There are four Sn(IV) centres which can be divided into two sorts, viz. two endocyclic and two exocyclic. The endo- and exocyclic Sn(IV) centres are linked by bidentate deprotonated methanol and μ(3)-O atoms. Each exocyclic Sn(IV) centre is also coordinated by a monodentate 2-[4-(2-hydroxy­benzyl­idene­amino)phen­yl]acetate ligand. Parts of the butyl groups were found to be disordered over two sets of sites. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971054/ /pubmed/21578042 http://dx.doi.org/10.1107/S1600536809038938 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Wenkuan
Yin, Handong
Wen, Liyuan
Wang, Daqi
Fan, Weidong
Octa­butyl­bis{(E)-2-[4-(2-hydroxy­benzyl­ideneamino)phen­yl]acetato}di-μ(2)-methoxo-di-μ(3)-oxido-tetra­tin(IV)
title Octa­butyl­bis{(E)-2-[4-(2-hydroxy­benzyl­ideneamino)phen­yl]acetato}di-μ(2)-methoxo-di-μ(3)-oxido-tetra­tin(IV)
title_full Octa­butyl­bis{(E)-2-[4-(2-hydroxy­benzyl­ideneamino)phen­yl]acetato}di-μ(2)-methoxo-di-μ(3)-oxido-tetra­tin(IV)
title_fullStr Octa­butyl­bis{(E)-2-[4-(2-hydroxy­benzyl­ideneamino)phen­yl]acetato}di-μ(2)-methoxo-di-μ(3)-oxido-tetra­tin(IV)
title_full_unstemmed Octa­butyl­bis{(E)-2-[4-(2-hydroxy­benzyl­ideneamino)phen­yl]acetato}di-μ(2)-methoxo-di-μ(3)-oxido-tetra­tin(IV)
title_short Octa­butyl­bis{(E)-2-[4-(2-hydroxy­benzyl­ideneamino)phen­yl]acetato}di-μ(2)-methoxo-di-μ(3)-oxido-tetra­tin(IV)
title_sort octa­butyl­bis{(e)-2-[4-(2-hydroxy­benzyl­ideneamino)phen­yl]acetato}di-μ(2)-methoxo-di-μ(3)-oxido-tetra­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971054/
https://www.ncbi.nlm.nih.gov/pubmed/21578042
http://dx.doi.org/10.1107/S1600536809038938
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