catena-Poly[[[acetonitrile­copper(I)]-bis­[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]-copper(I)-μ-1,2-di-4-pyridy­l­ethene] bis­(tetra­fluoridoborate)]

The title dinuclear copper(I) complex, {[Cu(2)(C(2)H(3)N)(C(12)H(10)N(2))(C(25)H(22)P(2))(2)](BF(4))(2)}(n), contains 1,2-di-4-pyridyl­ethene, bis­(diphenyl­phosphino)methane and acetonitrile ligands. The two Cu atoms, one with an N(2)P(2) ligand set and the other with an NP(2) ligand set, are bridg...

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Detalles Bibliográficos
Autores principales: Wang, Yufei, Gan, Xin, Jishu, Chen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971055/
https://www.ncbi.nlm.nih.gov/pubmed/21578112
http://dx.doi.org/10.1107/S1600536809040896
Descripción
Sumario:The title dinuclear copper(I) complex, {[Cu(2)(C(2)H(3)N)(C(12)H(10)N(2))(C(25)H(22)P(2))(2)](BF(4))(2)}(n), contains 1,2-di-4-pyridyl­ethene, bis­(diphenyl­phosphino)methane and acetonitrile ligands. The two Cu atoms, one with an N(2)P(2) ligand set and the other with an NP(2) ligand set, are bridged by two bis­(diphenyl­phosphino)methane ligands, forming an eight-membered ring.

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