N-(2,6-Dimethyl­phen­yl)maleamic acid

The asymmetric unit of the title compound, C(12)H(13)NO(3), contains two independent mol­ecules. The conformation of the N—H bond and the C=O bond in the amide segment are anti to each other. The mol­ecular conformation of each mol­ecule is stabilized by an intra­molecular O—H⋯O hydrogen bond. In th...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Tokarčík, Miroslav, Kožíšek, Jozef, Shakuntala, K., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971056/
https://www.ncbi.nlm.nih.gov/pubmed/21578399
http://dx.doi.org/10.1107/S1600536809042470
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author Gowda, B. Thimme
Tokarčík, Miroslav
Kožíšek, Jozef
Shakuntala, K.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Tokarčík, Miroslav
Kožíšek, Jozef
Shakuntala, K.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description The asymmetric unit of the title compound, C(12)H(13)NO(3), contains two independent mol­ecules. The conformation of the N—H bond and the C=O bond in the amide segment are anti to each other. The mol­ecular conformation of each mol­ecule is stabilized by an intra­molecular O—H⋯O hydrogen bond. In the crystal, mol­ecules are connected through intermolecular N—H⋯O hydrogen bonds. In addition, there is a carbon­yl–carbonyl dipolar inter­action with an O⋯C contact of 2.926 (3) Å.
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spelling pubmed-29710562010-12-30 N-(2,6-Dimethyl­phen­yl)maleamic acid Gowda, B. Thimme Tokarčík, Miroslav Kožíšek, Jozef Shakuntala, K. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(12)H(13)NO(3), contains two independent mol­ecules. The conformation of the N—H bond and the C=O bond in the amide segment are anti to each other. The mol­ecular conformation of each mol­ecule is stabilized by an intra­molecular O—H⋯O hydrogen bond. In the crystal, mol­ecules are connected through intermolecular N—H⋯O hydrogen bonds. In addition, there is a carbon­yl–carbonyl dipolar inter­action with an O⋯C contact of 2.926 (3) Å. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971056/ /pubmed/21578399 http://dx.doi.org/10.1107/S1600536809042470 Text en © Gowda et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Tokarčík, Miroslav
Kožíšek, Jozef
Shakuntala, K.
Fuess, Hartmut
N-(2,6-Dimethyl­phen­yl)maleamic acid
title N-(2,6-Dimethyl­phen­yl)maleamic acid
title_full N-(2,6-Dimethyl­phen­yl)maleamic acid
title_fullStr N-(2,6-Dimethyl­phen­yl)maleamic acid
title_full_unstemmed N-(2,6-Dimethyl­phen­yl)maleamic acid
title_short N-(2,6-Dimethyl­phen­yl)maleamic acid
title_sort n-(2,6-dimethyl­phen­yl)maleamic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971056/
https://www.ncbi.nlm.nih.gov/pubmed/21578399
http://dx.doi.org/10.1107/S1600536809042470
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AT tokarcikmiroslav n26dimethylphenylmaleamicacid
AT kozisekjozef n26dimethylphenylmaleamicacid
AT shakuntalak n26dimethylphenylmaleamicacid
AT fuesshartmut n26dimethylphenylmaleamicacid

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