Cargando…
5,5′-Dimethoxy-2,2′-[(nonane-1,9-diyldioxy)bis(nitrilomethylidyne)]diphenol
The molecule of the title compound, C(25)H(34)N(2)O(6), adopts a fully extended configuration. The oxime (—CH=N—O—) group is coplanar with the aromatic ring and the two benzene rings are almost parallel, making a dihedral angle of 0.16 (3)°. In the crystal structure, strong intramolecular O—H⋯N hy...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971058/ https://www.ncbi.nlm.nih.gov/pubmed/21578365 http://dx.doi.org/10.1107/S1600536809041038 |
Sumario: | The molecule of the title compound, C(25)H(34)N(2)O(6), adopts a fully extended configuration. The oxime (—CH=N—O—) group is coplanar with the aromatic ring and the two benzene rings are almost parallel, making a dihedral angle of 0.16 (3)°. In the crystal structure, strong intramolecular O—H⋯N hydrogen bonds generate six-membered S(6) ring motifs. Intermolecular C—H⋯O hydrogen bonds link each molecule to five others, forming an infinite three-dimensional supramolecular structure. The crystal is further stabilized by π–π stacking interactions between neighbouring benzene rings [centroid–centroid distance = 3.744 (2) Å]. |
---|