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5,5′-Dimeth­oxy-2,2′-[(nonane-1,9-diyldi­oxy)bis­(nitrilo­methyl­idyne)]diphenol

The mol­ecule of the title compound, C(25)H(34)N(2)O(6), adopts a fully extended configuration. The oxime (—CH=N—O—) group is coplanar with the aromatic ring and the two benzene rings are almost parallel, making a dihedral angle of 0.16 (3)°. In the crystal structure, strong intra­molecular O—H⋯N hy...

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Detalles Bibliográficos
Autores principales: Li, Li, Ma, Hong-Zheng, Gao, Su-Xia, Dong, Wen-Kui, Wu, Jian-Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971058/
https://www.ncbi.nlm.nih.gov/pubmed/21578365
http://dx.doi.org/10.1107/S1600536809041038
Descripción
Sumario:The mol­ecule of the title compound, C(25)H(34)N(2)O(6), adopts a fully extended configuration. The oxime (—CH=N—O—) group is coplanar with the aromatic ring and the two benzene rings are almost parallel, making a dihedral angle of 0.16 (3)°. In the crystal structure, strong intra­molecular O—H⋯N hydrogen bonds generate six-membered S(6) ring motifs. Inter­molecular C—H⋯O hydrogen bonds link each mol­ecule to five others, forming an infinite three-dimensional supra­molecular structure. The crystal is further stabilized by π–π stacking inter­actions between neighbouring benzene rings [centroid–centroid distance = 3.744 (2) Å].