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5,5′-Dimeth­oxy-2,2′-[(nonane-1,9-diyldi­oxy)bis­(nitrilo­methyl­idyne)]diphenol

The mol­ecule of the title compound, C(25)H(34)N(2)O(6), adopts a fully extended configuration. The oxime (—CH=N—O—) group is coplanar with the aromatic ring and the two benzene rings are almost parallel, making a dihedral angle of 0.16 (3)°. In the crystal structure, strong intra­molecular O—H⋯N hy...

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Detalles Bibliográficos
Autores principales: Li, Li, Ma, Hong-Zheng, Gao, Su-Xia, Dong, Wen-Kui, Wu, Jian-Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971058/
https://www.ncbi.nlm.nih.gov/pubmed/21578365
http://dx.doi.org/10.1107/S1600536809041038
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author Li, Li
Ma, Hong-Zheng
Gao, Su-Xia
Dong, Wen-Kui
Wu, Jian-Chao
author_facet Li, Li
Ma, Hong-Zheng
Gao, Su-Xia
Dong, Wen-Kui
Wu, Jian-Chao
author_sort Li, Li
collection PubMed
description The mol­ecule of the title compound, C(25)H(34)N(2)O(6), adopts a fully extended configuration. The oxime (—CH=N—O—) group is coplanar with the aromatic ring and the two benzene rings are almost parallel, making a dihedral angle of 0.16 (3)°. In the crystal structure, strong intra­molecular O—H⋯N hydrogen bonds generate six-membered S(6) ring motifs. Inter­molecular C—H⋯O hydrogen bonds link each mol­ecule to five others, forming an infinite three-dimensional supra­molecular structure. The crystal is further stabilized by π–π stacking inter­actions between neighbouring benzene rings [centroid–centroid distance = 3.744 (2) Å].
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spelling pubmed-29710582010-12-30 5,5′-Dimeth­oxy-2,2′-[(nonane-1,9-diyldi­oxy)bis­(nitrilo­methyl­idyne)]diphenol Li, Li Ma, Hong-Zheng Gao, Su-Xia Dong, Wen-Kui Wu, Jian-Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(25)H(34)N(2)O(6), adopts a fully extended configuration. The oxime (—CH=N—O—) group is coplanar with the aromatic ring and the two benzene rings are almost parallel, making a dihedral angle of 0.16 (3)°. In the crystal structure, strong intra­molecular O—H⋯N hydrogen bonds generate six-membered S(6) ring motifs. Inter­molecular C—H⋯O hydrogen bonds link each mol­ecule to five others, forming an infinite three-dimensional supra­molecular structure. The crystal is further stabilized by π–π stacking inter­actions between neighbouring benzene rings [centroid–centroid distance = 3.744 (2) Å]. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971058/ /pubmed/21578365 http://dx.doi.org/10.1107/S1600536809041038 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Li
Ma, Hong-Zheng
Gao, Su-Xia
Dong, Wen-Kui
Wu, Jian-Chao
5,5′-Dimeth­oxy-2,2′-[(nonane-1,9-diyldi­oxy)bis­(nitrilo­methyl­idyne)]diphenol
title 5,5′-Dimeth­oxy-2,2′-[(nonane-1,9-diyldi­oxy)bis­(nitrilo­methyl­idyne)]diphenol
title_full 5,5′-Dimeth­oxy-2,2′-[(nonane-1,9-diyldi­oxy)bis­(nitrilo­methyl­idyne)]diphenol
title_fullStr 5,5′-Dimeth­oxy-2,2′-[(nonane-1,9-diyldi­oxy)bis­(nitrilo­methyl­idyne)]diphenol
title_full_unstemmed 5,5′-Dimeth­oxy-2,2′-[(nonane-1,9-diyldi­oxy)bis­(nitrilo­methyl­idyne)]diphenol
title_short 5,5′-Dimeth­oxy-2,2′-[(nonane-1,9-diyldi­oxy)bis­(nitrilo­methyl­idyne)]diphenol
title_sort 5,5′-dimeth­oxy-2,2′-[(nonane-1,9-diyldi­oxy)bis­(nitrilo­methyl­idyne)]diphenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971058/
https://www.ncbi.nlm.nih.gov/pubmed/21578365
http://dx.doi.org/10.1107/S1600536809041038
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