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(2,2′-Bipyridine-κ(2) N,N′)dibromidopalladium(II) dichloromethane solvate
In the title compound, [PdBr(2)(C(10)H(8)N(2))]·CH(2)Cl(2), the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2′-bipyridine ligand and two bromide ions. The compound displays intramolecular C—H⋯Br hydrogen bonds and pairs of compl...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971059/ https://www.ncbi.nlm.nih.gov/pubmed/21578060 http://dx.doi.org/10.1107/S1600536809039701 |
Sumario: | In the title compound, [PdBr(2)(C(10)H(8)N(2))]·CH(2)Cl(2), the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2′-bipyridine ligand and two bromide ions. The compound displays intramolecular C—H⋯Br hydrogen bonds and pairs of complex molecules are assembled by intermolecular C—H⋯Br hydrogen bonds. These pairs are connected by additional C—H⋯Br hydrogen bonds, forming a layer structure extending parallel to (011). Intermolecular π–π interactions between the pyridine rings of the ligand are also present, the shortest centroid–centroid distance being 4.090 (9) Å. |
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