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(2,2′-Bipyridine-κ(2) N,N′)dibromidopalladium(II) dichloromethane solvate
In the title compound, [PdBr(2)(C(10)H(8)N(2))]·CH(2)Cl(2), the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2′-bipyridine ligand and two bromide ions. The compound displays intramolecular C—H⋯Br hydrogen bonds and pairs of compl...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971059/ https://www.ncbi.nlm.nih.gov/pubmed/21578060 http://dx.doi.org/10.1107/S1600536809039701 |
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author | Kim, Nam-Ho Ha, Kwang |
author_facet | Kim, Nam-Ho Ha, Kwang |
author_sort | Kim, Nam-Ho |
collection | PubMed |
description | In the title compound, [PdBr(2)(C(10)H(8)N(2))]·CH(2)Cl(2), the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2′-bipyridine ligand and two bromide ions. The compound displays intramolecular C—H⋯Br hydrogen bonds and pairs of complex molecules are assembled by intermolecular C—H⋯Br hydrogen bonds. These pairs are connected by additional C—H⋯Br hydrogen bonds, forming a layer structure extending parallel to (011). Intermolecular π–π interactions between the pyridine rings of the ligand are also present, the shortest centroid–centroid distance being 4.090 (9) Å. |
format | Text |
id | pubmed-2971059 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29710592010-12-30 (2,2′-Bipyridine-κ(2) N,N′)dibromidopalladium(II) dichloromethane solvate Kim, Nam-Ho Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdBr(2)(C(10)H(8)N(2))]·CH(2)Cl(2), the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2′-bipyridine ligand and two bromide ions. The compound displays intramolecular C—H⋯Br hydrogen bonds and pairs of complex molecules are assembled by intermolecular C—H⋯Br hydrogen bonds. These pairs are connected by additional C—H⋯Br hydrogen bonds, forming a layer structure extending parallel to (011). Intermolecular π–π interactions between the pyridine rings of the ligand are also present, the shortest centroid–centroid distance being 4.090 (9) Å. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971059/ /pubmed/21578060 http://dx.doi.org/10.1107/S1600536809039701 Text en © Kim and Ha 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kim, Nam-Ho Ha, Kwang (2,2′-Bipyridine-κ(2) N,N′)dibromidopalladium(II) dichloromethane solvate |
title | (2,2′-Bipyridine-κ(2)
N,N′)dibromidopalladium(II) dichloromethane solvate |
title_full | (2,2′-Bipyridine-κ(2)
N,N′)dibromidopalladium(II) dichloromethane solvate |
title_fullStr | (2,2′-Bipyridine-κ(2)
N,N′)dibromidopalladium(II) dichloromethane solvate |
title_full_unstemmed | (2,2′-Bipyridine-κ(2)
N,N′)dibromidopalladium(II) dichloromethane solvate |
title_short | (2,2′-Bipyridine-κ(2)
N,N′)dibromidopalladium(II) dichloromethane solvate |
title_sort | (2,2′-bipyridine-κ(2)
n,n′)dibromidopalladium(ii) dichloromethane solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971059/ https://www.ncbi.nlm.nih.gov/pubmed/21578060 http://dx.doi.org/10.1107/S1600536809039701 |
work_keys_str_mv | AT kimnamho 22bipyridinek2nndibromidopalladiumiidichloromethanesolvate AT hakwang 22bipyridinek2nndibromidopalladiumiidichloromethanesolvate |