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(2,2′-Bipyridine-κ(2) N,N′)dibromido­palladium(II) dichloro­methane solvate

In the title compound, [PdBr(2)(C(10)H(8)N(2))]·CH(2)Cl(2), the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2′-bipyridine ligand and two bromide ions. The compound displays intra­molecular C—H⋯Br hydrogen bonds and pairs of compl...

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Autores principales: Kim, Nam-Ho, Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971059/
https://www.ncbi.nlm.nih.gov/pubmed/21578060
http://dx.doi.org/10.1107/S1600536809039701
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author Kim, Nam-Ho
Ha, Kwang
author_facet Kim, Nam-Ho
Ha, Kwang
author_sort Kim, Nam-Ho
collection PubMed
description In the title compound, [PdBr(2)(C(10)H(8)N(2))]·CH(2)Cl(2), the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2′-bipyridine ligand and two bromide ions. The compound displays intra­molecular C—H⋯Br hydrogen bonds and pairs of complex mol­ecules are assembled by inter­molecular C—H⋯Br hydrogen bonds. These pairs are connected by additional C—H⋯Br hydrogen bonds, forming a layer structure extending parallel to (011). Inter­molecular π–π inter­actions between the pyridine rings of the ligand are also present, the shortest centroid–centroid distance being 4.090 (9) Å.
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spelling pubmed-29710592010-12-30 (2,2′-Bipyridine-κ(2) N,N′)dibromido­palladium(II) dichloro­methane solvate Kim, Nam-Ho Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdBr(2)(C(10)H(8)N(2))]·CH(2)Cl(2), the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2′-bipyridine ligand and two bromide ions. The compound displays intra­molecular C—H⋯Br hydrogen bonds and pairs of complex mol­ecules are assembled by inter­molecular C—H⋯Br hydrogen bonds. These pairs are connected by additional C—H⋯Br hydrogen bonds, forming a layer structure extending parallel to (011). Inter­molecular π–π inter­actions between the pyridine rings of the ligand are also present, the shortest centroid–centroid distance being 4.090 (9) Å. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971059/ /pubmed/21578060 http://dx.doi.org/10.1107/S1600536809039701 Text en © Kim and Ha 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kim, Nam-Ho
Ha, Kwang
(2,2′-Bipyridine-κ(2) N,N′)dibromido­palladium(II) dichloro­methane solvate
title (2,2′-Bipyridine-κ(2) N,N′)dibromido­palladium(II) dichloro­methane solvate
title_full (2,2′-Bipyridine-κ(2) N,N′)dibromido­palladium(II) dichloro­methane solvate
title_fullStr (2,2′-Bipyridine-κ(2) N,N′)dibromido­palladium(II) dichloro­methane solvate
title_full_unstemmed (2,2′-Bipyridine-κ(2) N,N′)dibromido­palladium(II) dichloro­methane solvate
title_short (2,2′-Bipyridine-κ(2) N,N′)dibromido­palladium(II) dichloro­methane solvate
title_sort (2,2′-bipyridine-κ(2) n,n′)dibromido­palladium(ii) dichloro­methane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971059/
https://www.ncbi.nlm.nih.gov/pubmed/21578060
http://dx.doi.org/10.1107/S1600536809039701
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