[N,N,N′,N′-Tetra­kis(benzimidazol-2-yl­meth­yl)ethane-1,2-diamine]copper(II) sulfate monohydrate

In the title compound, [Cu(C(34)H(32)N(10))]SO(4)·H(2)O, the Cu(II) ion is coordinated by six N atoms of a hexa­dentate N,N,N′,N′-tetra­kis(benzimidazol-2-ylmeth­yl)ethane-1,2-diamine (EDTB) ligand, in a distorted octa­hedral environment. In the crystal structure, inter­molecular N—H⋯O and weak C—H⋯...

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Detalles Bibliográficos
Autores principales: Xiao, Zuo-an, Zhan, Dan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971061/
https://www.ncbi.nlm.nih.gov/pubmed/21578188
http://dx.doi.org/10.1107/S1600536809043517
Descripción
Sumario:In the title compound, [Cu(C(34)H(32)N(10))]SO(4)·H(2)O, the Cu(II) ion is coordinated by six N atoms of a hexa­dentate N,N,N′,N′-tetra­kis(benzimidazol-2-ylmeth­yl)ethane-1,2-diamine (EDTB) ligand, in a distorted octa­hedral environment. In the crystal structure, inter­molecular N—H⋯O and weak C—H⋯O hydrogen bonds connect the cations, anions and water mol­ecules into a three-dimensional network. The O atoms of the anion are disordered over two sites with refined occupancies of 0.711 (2) and 0.289 (2).

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