[N,N,N′,N′-Tetra­kis(benzimidazol-2-yl­meth­yl)ethane-1,2-diamine]copper(II) sulfate monohydrate

In the title compound, [Cu(C(34)H(32)N(10))]SO(4)·H(2)O, the Cu(II) ion is coordinated by six N atoms of a hexa­dentate N,N,N′,N′-tetra­kis(benzimidazol-2-ylmeth­yl)ethane-1,2-diamine (EDTB) ligand, in a distorted octa­hedral environment. In the crystal structure, inter­molecular N—H⋯O and weak C—H⋯...

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Detalles Bibliográficos
Autores principales: Xiao, Zuo-an, Zhan, Dan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971061/
https://www.ncbi.nlm.nih.gov/pubmed/21578188
http://dx.doi.org/10.1107/S1600536809043517
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author Xiao, Zuo-an
Zhan, Dan
author_facet Xiao, Zuo-an
Zhan, Dan
author_sort Xiao, Zuo-an
collection PubMed
description In the title compound, [Cu(C(34)H(32)N(10))]SO(4)·H(2)O, the Cu(II) ion is coordinated by six N atoms of a hexa­dentate N,N,N′,N′-tetra­kis(benzimidazol-2-ylmeth­yl)ethane-1,2-diamine (EDTB) ligand, in a distorted octa­hedral environment. In the crystal structure, inter­molecular N—H⋯O and weak C—H⋯O hydrogen bonds connect the cations, anions and water mol­ecules into a three-dimensional network. The O atoms of the anion are disordered over two sites with refined occupancies of 0.711 (2) and 0.289 (2).
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spelling pubmed-29710612010-12-30 [N,N,N′,N′-Tetra­kis(benzimidazol-2-yl­meth­yl)ethane-1,2-diamine]copper(II) sulfate monohydrate Xiao, Zuo-an Zhan, Dan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(34)H(32)N(10))]SO(4)·H(2)O, the Cu(II) ion is coordinated by six N atoms of a hexa­dentate N,N,N′,N′-tetra­kis(benzimidazol-2-ylmeth­yl)ethane-1,2-diamine (EDTB) ligand, in a distorted octa­hedral environment. In the crystal structure, inter­molecular N—H⋯O and weak C—H⋯O hydrogen bonds connect the cations, anions and water mol­ecules into a three-dimensional network. The O atoms of the anion are disordered over two sites with refined occupancies of 0.711 (2) and 0.289 (2). International Union of Crystallography 2009-10-28 /pmc/articles/PMC2971061/ /pubmed/21578188 http://dx.doi.org/10.1107/S1600536809043517 Text en © Xiao and Zhan 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xiao, Zuo-an
Zhan, Dan
[N,N,N′,N′-Tetra­kis(benzimidazol-2-yl­meth­yl)ethane-1,2-diamine]copper(II) sulfate monohydrate
title [N,N,N′,N′-Tetra­kis(benzimidazol-2-yl­meth­yl)ethane-1,2-diamine]copper(II) sulfate monohydrate
title_full [N,N,N′,N′-Tetra­kis(benzimidazol-2-yl­meth­yl)ethane-1,2-diamine]copper(II) sulfate monohydrate
title_fullStr [N,N,N′,N′-Tetra­kis(benzimidazol-2-yl­meth­yl)ethane-1,2-diamine]copper(II) sulfate monohydrate
title_full_unstemmed [N,N,N′,N′-Tetra­kis(benzimidazol-2-yl­meth­yl)ethane-1,2-diamine]copper(II) sulfate monohydrate
title_short [N,N,N′,N′-Tetra­kis(benzimidazol-2-yl­meth­yl)ethane-1,2-diamine]copper(II) sulfate monohydrate
title_sort [n,n,n′,n′-tetra­kis(benzimidazol-2-yl­meth­yl)ethane-1,2-diamine]copper(ii) sulfate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971061/
https://www.ncbi.nlm.nih.gov/pubmed/21578188
http://dx.doi.org/10.1107/S1600536809043517
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