N-[2-(2-Bromo­benzyl­amino)phen­yl]-N-butylformamide

The title compound, C(18)H(21)BrN(2)O, crystallizes with two mol­ecules (A and B) in the asymmetric unit (Z′ = 2). The major differences between the two mol­ecules are related to the conformations adopted by their n-butyl side chains. The phenyl rings in both mol­ecules are almost perpendicular, mak...

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Detalles Bibliográficos
Autores principales: Manjare, Sudesh T., Butcher, Ray J., Singh, Harkesh B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971065/
https://www.ncbi.nlm.nih.gov/pubmed/21578417
http://dx.doi.org/10.1107/S1600536809042883
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author Manjare, Sudesh T.
Butcher, Ray J.
Singh, Harkesh B.
author_facet Manjare, Sudesh T.
Butcher, Ray J.
Singh, Harkesh B.
author_sort Manjare, Sudesh T.
collection PubMed
description The title compound, C(18)H(21)BrN(2)O, crystallizes with two mol­ecules (A and B) in the asymmetric unit (Z′ = 2). The major differences between the two mol­ecules are related to the conformations adopted by their n-butyl side chains. The phenyl rings in both mol­ecules are almost perpendicular, making dihedral angles of 79.2 (3) and 80.8 (3)°. The amide units are planar (r.m.s. deviations of 0.0018 and 0.021 Å) and almost perpendicular to the phenyl rings to which they are attached [dihedral angles of 68.9 (4) and 71.1 (4)°]. In the crystal, molecules A and B each form only an intermolecular N—H⋯O hydrogen bond with an adjacent molecule of the same kind. There are no significant intermolecular interactions between molecules A and B.
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spelling pubmed-29710652010-12-30 N-[2-(2-Bromo­benzyl­amino)phen­yl]-N-butylformamide Manjare, Sudesh T. Butcher, Ray J. Singh, Harkesh B. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(21)BrN(2)O, crystallizes with two mol­ecules (A and B) in the asymmetric unit (Z′ = 2). The major differences between the two mol­ecules are related to the conformations adopted by their n-butyl side chains. The phenyl rings in both mol­ecules are almost perpendicular, making dihedral angles of 79.2 (3) and 80.8 (3)°. The amide units are planar (r.m.s. deviations of 0.0018 and 0.021 Å) and almost perpendicular to the phenyl rings to which they are attached [dihedral angles of 68.9 (4) and 71.1 (4)°]. In the crystal, molecules A and B each form only an intermolecular N—H⋯O hydrogen bond with an adjacent molecule of the same kind. There are no significant intermolecular interactions between molecules A and B. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971065/ /pubmed/21578417 http://dx.doi.org/10.1107/S1600536809042883 Text en © Manjare et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Manjare, Sudesh T.
Butcher, Ray J.
Singh, Harkesh B.
N-[2-(2-Bromo­benzyl­amino)phen­yl]-N-butylformamide
title N-[2-(2-Bromo­benzyl­amino)phen­yl]-N-butylformamide
title_full N-[2-(2-Bromo­benzyl­amino)phen­yl]-N-butylformamide
title_fullStr N-[2-(2-Bromo­benzyl­amino)phen­yl]-N-butylformamide
title_full_unstemmed N-[2-(2-Bromo­benzyl­amino)phen­yl]-N-butylformamide
title_short N-[2-(2-Bromo­benzyl­amino)phen­yl]-N-butylformamide
title_sort n-[2-(2-bromo­benzyl­amino)phen­yl]-n-butylformamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971065/
https://www.ncbi.nlm.nih.gov/pubmed/21578417
http://dx.doi.org/10.1107/S1600536809042883
work_keys_str_mv AT manjaresudesht n22bromobenzylaminophenylnbutylformamide
AT butcherrayj n22bromobenzylaminophenylnbutylformamide
AT singhharkeshb n22bromobenzylaminophenylnbutylformamide

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