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Poly[[diaqua­bis(μ(2)-isonicotinato-κ(2) N:O)bis­(μ(3)-isonicotinato-κ(3) N:O:O′)neodymium(III)disilver(I)] nitrate monohydrate]

In the title complex, {[Ag(2)Nd(C(6)H(4)NO(2))(4)(H(2)O)(2)]NO(3)·H(2)O}(n), the Nd(III) ion is coordinated by eight O atoms from six isonicotinate ligands and two water mol­ecules in a distorted square anti­prismatic geometry. Each Ag(I) ion is coordinated by two N atoms from two different isonicot...

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Autores principales: Zhan, Qing-Guang, Huang, Jie-Xuan, Zeng, Rong-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971066/
https://www.ncbi.nlm.nih.gov/pubmed/21578167
http://dx.doi.org/10.1107/S1600536809042342
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author Zhan, Qing-Guang
Huang, Jie-Xuan
Zeng, Rong-Hua
author_facet Zhan, Qing-Guang
Huang, Jie-Xuan
Zeng, Rong-Hua
author_sort Zhan, Qing-Guang
collection PubMed
description In the title complex, {[Ag(2)Nd(C(6)H(4)NO(2))(4)(H(2)O)(2)]NO(3)·H(2)O}(n), the Nd(III) ion is coordinated by eight O atoms from six isonicotinate ligands and two water mol­ecules in a distorted square anti­prismatic geometry. Each Ag(I) ion is coordinated by two N atoms from two different isonicotinate ligands. The crystal structure exhibits a two-dimensional heterometallic polymeric layer. O—H⋯O hydrogen bonds involving the coordinated and uncoordinated water mol­ecules and intra­layer π–π inter­actions between the pyridine rings [centroid–centroid distances = 3.571 (2) and 3.569 (2) Å] are observed. Each layer inter­acts with two neighboring ones via Ag⋯O(H(2)O) contacts and inter­layer π–π inter­actions [centroid–centroid distances = 3.479 (3) to 3.530 (3) Å], leading to a three-dimensional supra­molecular network.
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spelling pubmed-29710662010-12-30 Poly[[diaqua­bis(μ(2)-isonicotinato-κ(2) N:O)bis­(μ(3)-isonicotinato-κ(3) N:O:O′)neodymium(III)disilver(I)] nitrate monohydrate] Zhan, Qing-Guang Huang, Jie-Xuan Zeng, Rong-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Ag(2)Nd(C(6)H(4)NO(2))(4)(H(2)O)(2)]NO(3)·H(2)O}(n), the Nd(III) ion is coordinated by eight O atoms from six isonicotinate ligands and two water mol­ecules in a distorted square anti­prismatic geometry. Each Ag(I) ion is coordinated by two N atoms from two different isonicotinate ligands. The crystal structure exhibits a two-dimensional heterometallic polymeric layer. O—H⋯O hydrogen bonds involving the coordinated and uncoordinated water mol­ecules and intra­layer π–π inter­actions between the pyridine rings [centroid–centroid distances = 3.571 (2) and 3.569 (2) Å] are observed. Each layer inter­acts with two neighboring ones via Ag⋯O(H(2)O) contacts and inter­layer π–π inter­actions [centroid–centroid distances = 3.479 (3) to 3.530 (3) Å], leading to a three-dimensional supra­molecular network. International Union of Crystallography 2009-10-28 /pmc/articles/PMC2971066/ /pubmed/21578167 http://dx.doi.org/10.1107/S1600536809042342 Text en © Zhan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhan, Qing-Guang
Huang, Jie-Xuan
Zeng, Rong-Hua
Poly[[diaqua­bis(μ(2)-isonicotinato-κ(2) N:O)bis­(μ(3)-isonicotinato-κ(3) N:O:O′)neodymium(III)disilver(I)] nitrate monohydrate]
title Poly[[diaqua­bis(μ(2)-isonicotinato-κ(2) N:O)bis­(μ(3)-isonicotinato-κ(3) N:O:O′)neodymium(III)disilver(I)] nitrate monohydrate]
title_full Poly[[diaqua­bis(μ(2)-isonicotinato-κ(2) N:O)bis­(μ(3)-isonicotinato-κ(3) N:O:O′)neodymium(III)disilver(I)] nitrate monohydrate]
title_fullStr Poly[[diaqua­bis(μ(2)-isonicotinato-κ(2) N:O)bis­(μ(3)-isonicotinato-κ(3) N:O:O′)neodymium(III)disilver(I)] nitrate monohydrate]
title_full_unstemmed Poly[[diaqua­bis(μ(2)-isonicotinato-κ(2) N:O)bis­(μ(3)-isonicotinato-κ(3) N:O:O′)neodymium(III)disilver(I)] nitrate monohydrate]
title_short Poly[[diaqua­bis(μ(2)-isonicotinato-κ(2) N:O)bis­(μ(3)-isonicotinato-κ(3) N:O:O′)neodymium(III)disilver(I)] nitrate monohydrate]
title_sort poly[[diaqua­bis(μ(2)-isonicotinato-κ(2) n:o)bis­(μ(3)-isonicotinato-κ(3) n:o:o′)neodymium(iii)disilver(i)] nitrate monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971066/
https://www.ncbi.nlm.nih.gov/pubmed/21578167
http://dx.doi.org/10.1107/S1600536809042342
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