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Poly[[diaquabis(μ(2)-isonicotinato-κ(2) N:O)bis(μ(3)-isonicotinato-κ(3) N:O:O′)neodymium(III)disilver(I)] nitrate monohydrate]
In the title complex, {[Ag(2)Nd(C(6)H(4)NO(2))(4)(H(2)O)(2)]NO(3)·H(2)O}(n), the Nd(III) ion is coordinated by eight O atoms from six isonicotinate ligands and two water molecules in a distorted square antiprismatic geometry. Each Ag(I) ion is coordinated by two N atoms from two different isonicot...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971066/ https://www.ncbi.nlm.nih.gov/pubmed/21578167 http://dx.doi.org/10.1107/S1600536809042342 |
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author | Zhan, Qing-Guang Huang, Jie-Xuan Zeng, Rong-Hua |
author_facet | Zhan, Qing-Guang Huang, Jie-Xuan Zeng, Rong-Hua |
author_sort | Zhan, Qing-Guang |
collection | PubMed |
description | In the title complex, {[Ag(2)Nd(C(6)H(4)NO(2))(4)(H(2)O)(2)]NO(3)·H(2)O}(n), the Nd(III) ion is coordinated by eight O atoms from six isonicotinate ligands and two water molecules in a distorted square antiprismatic geometry. Each Ag(I) ion is coordinated by two N atoms from two different isonicotinate ligands. The crystal structure exhibits a two-dimensional heterometallic polymeric layer. O—H⋯O hydrogen bonds involving the coordinated and uncoordinated water molecules and intralayer π–π interactions between the pyridine rings [centroid–centroid distances = 3.571 (2) and 3.569 (2) Å] are observed. Each layer interacts with two neighboring ones via Ag⋯O(H(2)O) contacts and interlayer π–π interactions [centroid–centroid distances = 3.479 (3) to 3.530 (3) Å], leading to a three-dimensional supramolecular network. |
format | Text |
id | pubmed-2971066 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29710662010-12-30 Poly[[diaquabis(μ(2)-isonicotinato-κ(2) N:O)bis(μ(3)-isonicotinato-κ(3) N:O:O′)neodymium(III)disilver(I)] nitrate monohydrate] Zhan, Qing-Guang Huang, Jie-Xuan Zeng, Rong-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Ag(2)Nd(C(6)H(4)NO(2))(4)(H(2)O)(2)]NO(3)·H(2)O}(n), the Nd(III) ion is coordinated by eight O atoms from six isonicotinate ligands and two water molecules in a distorted square antiprismatic geometry. Each Ag(I) ion is coordinated by two N atoms from two different isonicotinate ligands. The crystal structure exhibits a two-dimensional heterometallic polymeric layer. O—H⋯O hydrogen bonds involving the coordinated and uncoordinated water molecules and intralayer π–π interactions between the pyridine rings [centroid–centroid distances = 3.571 (2) and 3.569 (2) Å] are observed. Each layer interacts with two neighboring ones via Ag⋯O(H(2)O) contacts and interlayer π–π interactions [centroid–centroid distances = 3.479 (3) to 3.530 (3) Å], leading to a three-dimensional supramolecular network. International Union of Crystallography 2009-10-28 /pmc/articles/PMC2971066/ /pubmed/21578167 http://dx.doi.org/10.1107/S1600536809042342 Text en © Zhan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhan, Qing-Guang Huang, Jie-Xuan Zeng, Rong-Hua Poly[[diaquabis(μ(2)-isonicotinato-κ(2) N:O)bis(μ(3)-isonicotinato-κ(3) N:O:O′)neodymium(III)disilver(I)] nitrate monohydrate] |
title | Poly[[diaquabis(μ(2)-isonicotinato-κ(2)
N:O)bis(μ(3)-isonicotinato-κ(3)
N:O:O′)neodymium(III)disilver(I)] nitrate monohydrate] |
title_full | Poly[[diaquabis(μ(2)-isonicotinato-κ(2)
N:O)bis(μ(3)-isonicotinato-κ(3)
N:O:O′)neodymium(III)disilver(I)] nitrate monohydrate] |
title_fullStr | Poly[[diaquabis(μ(2)-isonicotinato-κ(2)
N:O)bis(μ(3)-isonicotinato-κ(3)
N:O:O′)neodymium(III)disilver(I)] nitrate monohydrate] |
title_full_unstemmed | Poly[[diaquabis(μ(2)-isonicotinato-κ(2)
N:O)bis(μ(3)-isonicotinato-κ(3)
N:O:O′)neodymium(III)disilver(I)] nitrate monohydrate] |
title_short | Poly[[diaquabis(μ(2)-isonicotinato-κ(2)
N:O)bis(μ(3)-isonicotinato-κ(3)
N:O:O′)neodymium(III)disilver(I)] nitrate monohydrate] |
title_sort | poly[[diaquabis(μ(2)-isonicotinato-κ(2)
n:o)bis(μ(3)-isonicotinato-κ(3)
n:o:o′)neodymium(iii)disilver(i)] nitrate monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971066/ https://www.ncbi.nlm.nih.gov/pubmed/21578167 http://dx.doi.org/10.1107/S1600536809042342 |
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