N-(4-Chloro­phen­yl)-3-methyl­benzamide

In the structure of the title compound, C(14)H(12)ClNO, the conformations of the N—H and C=O bonds are anti to each other. Furthermore, the conformation of the C=O bond is syn to the meta-methyl group in the benzoyl ring. The central –NH—C(=O)– amido group makes a dihedral angle of 32.4 (1)° with th...

Descripción completa

Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Tokarčík, Miroslav, Kožíšek, Jozef, Rodrigues, Vinola Zeena, Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971070/
https://www.ncbi.nlm.nih.gov/pubmed/21578371
http://dx.doi.org/10.1107/S1600536809041956
_version_ 1782190539269996544
author Gowda, B. Thimme
Tokarčík, Miroslav
Kožíšek, Jozef
Rodrigues, Vinola Zeena
Fuess, Hartmut
author_facet Gowda, B. Thimme
Tokarčík, Miroslav
Kožíšek, Jozef
Rodrigues, Vinola Zeena
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description In the structure of the title compound, C(14)H(12)ClNO, the conformations of the N—H and C=O bonds are anti to each other. Furthermore, the conformation of the C=O bond is syn to the meta-methyl group in the benzoyl ring. The central –NH—C(=O)– amido group makes a dihedral angle of 32.4 (1)° with the benzoyl ring and 36.1 (1)° with the anilino ring. The dihedral angle between the two benzene rings is 68.4 (1)°. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains running along the a axis
format Text
id pubmed-2971070
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29710702010-12-30 N-(4-Chloro­phen­yl)-3-methyl­benzamide Gowda, B. Thimme Tokarčík, Miroslav Kožíšek, Jozef Rodrigues, Vinola Zeena Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the structure of the title compound, C(14)H(12)ClNO, the conformations of the N—H and C=O bonds are anti to each other. Furthermore, the conformation of the C=O bond is syn to the meta-methyl group in the benzoyl ring. The central –NH—C(=O)– amido group makes a dihedral angle of 32.4 (1)° with the benzoyl ring and 36.1 (1)° with the anilino ring. The dihedral angle between the two benzene rings is 68.4 (1)°. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains running along the a axis International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971070/ /pubmed/21578371 http://dx.doi.org/10.1107/S1600536809041956 Text en © Gowda et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Tokarčík, Miroslav
Kožíšek, Jozef
Rodrigues, Vinola Zeena
Fuess, Hartmut
N-(4-Chloro­phen­yl)-3-methyl­benzamide
title N-(4-Chloro­phen­yl)-3-methyl­benzamide
title_full N-(4-Chloro­phen­yl)-3-methyl­benzamide
title_fullStr N-(4-Chloro­phen­yl)-3-methyl­benzamide
title_full_unstemmed N-(4-Chloro­phen­yl)-3-methyl­benzamide
title_short N-(4-Chloro­phen­yl)-3-methyl­benzamide
title_sort n-(4-chloro­phen­yl)-3-methyl­benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971070/
https://www.ncbi.nlm.nih.gov/pubmed/21578371
http://dx.doi.org/10.1107/S1600536809041956
work_keys_str_mv AT gowdabthimme n4chlorophenyl3methylbenzamide
AT tokarcikmiroslav n4chlorophenyl3methylbenzamide
AT kozisekjozef n4chlorophenyl3methylbenzamide
AT rodriguesvinolazeena n4chlorophenyl3methylbenzamide
AT fuesshartmut n4chlorophenyl3methylbenzamide

Ejemplares similares