Cargando…
Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) bis(perchlorate)
In the title complex, [Cd(C(14)H(9)N(5))(2)](ClO(4))(2), the Cd(II) ion is coordinated by two tridentate 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligands in a distorted octahedral CdN(6) environment. In both 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligands, the 1,2,4-triazolyl ring and th...
Autor principal: | |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971072/ https://www.ncbi.nlm.nih.gov/pubmed/21578051 http://dx.doi.org/10.1107/S1600536809038768 |
_version_ | 1782190539749195776 |
---|---|
author | Li, Hong Liang |
author_facet | Li, Hong Liang |
author_sort | Li, Hong Liang |
collection | PubMed |
description | In the title complex, [Cd(C(14)H(9)N(5))(2)](ClO(4))(2), the Cd(II) ion is coordinated by two tridentate 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligands in a distorted octahedral CdN(6) environment. In both 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligands, the 1,2,4-triazolyl ring and the 1,10-phenanthroline ring system are essentially coplanar [maximun deviations of 0.136 (7) and 0.273 (5) Å, respectively]. The dihedral angle between the mean planes of the ligands is 89.65 (4)°. In the crystal structure, there is a weak π–π stacking interaction between a pyridine ring and a symmetry-related benzene ring with a centroid–centroid distance of 3.772 (3) Å. |
format | Text |
id | pubmed-2971072 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29710722010-12-30 Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) bis(perchlorate) Li, Hong Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(C(14)H(9)N(5))(2)](ClO(4))(2), the Cd(II) ion is coordinated by two tridentate 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligands in a distorted octahedral CdN(6) environment. In both 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligands, the 1,2,4-triazolyl ring and the 1,10-phenanthroline ring system are essentially coplanar [maximun deviations of 0.136 (7) and 0.273 (5) Å, respectively]. The dihedral angle between the mean planes of the ligands is 89.65 (4)°. In the crystal structure, there is a weak π–π stacking interaction between a pyridine ring and a symmetry-related benzene ring with a centroid–centroid distance of 3.772 (3) Å. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971072/ /pubmed/21578051 http://dx.doi.org/10.1107/S1600536809038768 Text en © Hong Liang Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Hong Liang Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) bis(perchlorate) |
title | Bis[2-(1H-1,2,4-triazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]cadmium(II) bis(perchlorate) |
title_full | Bis[2-(1H-1,2,4-triazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]cadmium(II) bis(perchlorate) |
title_fullStr | Bis[2-(1H-1,2,4-triazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]cadmium(II) bis(perchlorate) |
title_full_unstemmed | Bis[2-(1H-1,2,4-triazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]cadmium(II) bis(perchlorate) |
title_short | Bis[2-(1H-1,2,4-triazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]cadmium(II) bis(perchlorate) |
title_sort | bis[2-(1h-1,2,4-triazol-1-yl-κn
(2))-1,10-phenanthroline-κ(2)
n,n′]cadmium(ii) bis(perchlorate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971072/ https://www.ncbi.nlm.nih.gov/pubmed/21578051 http://dx.doi.org/10.1107/S1600536809038768 |
work_keys_str_mv | AT lihongliang bis21h124triazol1ylkn2110phenanthrolinek2nncadmiumiibisperchlorate |