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Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) bis­(perchlorate)

In the title complex, [Cd(C(14)H(9)N(5))(2)](ClO(4))(2), the Cd(II) ion is coordinated by two tridentate 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligands in a distorted octa­hedral CdN(6) environment. In both 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligands, the 1,2,4-triazolyl ring and th...

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Detalles Bibliográficos
Autor principal: Li, Hong Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971072/
https://www.ncbi.nlm.nih.gov/pubmed/21578051
http://dx.doi.org/10.1107/S1600536809038768
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author Li, Hong Liang
author_facet Li, Hong Liang
author_sort Li, Hong Liang
collection PubMed
description In the title complex, [Cd(C(14)H(9)N(5))(2)](ClO(4))(2), the Cd(II) ion is coordinated by two tridentate 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligands in a distorted octa­hedral CdN(6) environment. In both 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligands, the 1,2,4-triazolyl ring and the 1,10-phenanthroline ring system are essentially coplanar [maximun deviations of 0.136 (7) and 0.273 (5) Å, respectively]. The dihedral angle between the mean planes of the ligands is 89.65 (4)°. In the crystal structure, there is a weak π–π stacking inter­action between a pyridine ring and a symmetry-related benzene ring with a centroid–centroid distance of 3.772 (3) Å.
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spelling pubmed-29710722010-12-30 Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) bis­(perchlorate) Li, Hong Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(C(14)H(9)N(5))(2)](ClO(4))(2), the Cd(II) ion is coordinated by two tridentate 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligands in a distorted octa­hedral CdN(6) environment. In both 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline ligands, the 1,2,4-triazolyl ring and the 1,10-phenanthroline ring system are essentially coplanar [maximun deviations of 0.136 (7) and 0.273 (5) Å, respectively]. The dihedral angle between the mean planes of the ligands is 89.65 (4)°. In the crystal structure, there is a weak π–π stacking inter­action between a pyridine ring and a symmetry-related benzene ring with a centroid–centroid distance of 3.772 (3) Å. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971072/ /pubmed/21578051 http://dx.doi.org/10.1107/S1600536809038768 Text en © Hong Liang Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Hong Liang
Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) bis­(perchlorate)
title Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) bis­(perchlorate)
title_full Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) bis­(perchlorate)
title_fullStr Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) bis­(perchlorate)
title_full_unstemmed Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) bis­(perchlorate)
title_short Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]cadmium(II) bis­(perchlorate)
title_sort bis[2-(1h-1,2,4-triazol-1-yl-κn (2))-1,10-phenanthroline-κ(2) n,n′]cadmium(ii) bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971072/
https://www.ncbi.nlm.nih.gov/pubmed/21578051
http://dx.doi.org/10.1107/S1600536809038768
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