(4-Bromo­phen­yl)(1H-indol-7-yl)methanone

In the crystal, the mol­ecules of the title compound, C(15)H(10)BrNO, are connected into centrosymmetric dimers by pairs of N—H⋯O hydrogen bonds. The dihedral angle between the planes of indole ring system and benzene ring is 50.13 (5)°. The indole plane is significantly less twisted from the plane...

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Detalles Bibliográficos
Autores principales: Dutkiewicz, Grzegorz, Chidan Kumar, C. S., Yathirajan, H. S., Kubicki, Maciej
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971073/
https://www.ncbi.nlm.nih.gov/pubmed/21578509
http://dx.doi.org/10.1107/S1600536809040914
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author Dutkiewicz, Grzegorz
Chidan Kumar, C. S.
Yathirajan, H. S.
Kubicki, Maciej
author_facet Dutkiewicz, Grzegorz
Chidan Kumar, C. S.
Yathirajan, H. S.
Kubicki, Maciej
author_sort Dutkiewicz, Grzegorz
collection PubMed
description In the crystal, the mol­ecules of the title compound, C(15)H(10)BrNO, are connected into centrosymmetric dimers by pairs of N—H⋯O hydrogen bonds. The dihedral angle between the planes of indole ring system and benzene ring is 50.13 (5)°. The indole plane is significantly less twisted from the plane of the central C—C(=O)—C bridge than the benzene plane [dihedral angles = 15.51 (3) and 40.13 (7)°, respectively]. The bond angles within the benzene ring show an approximately additive effect of the influence of both substituents.
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spelling pubmed-29710732010-12-30 (4-Bromo­phen­yl)(1H-indol-7-yl)methanone Dutkiewicz, Grzegorz Chidan Kumar, C. S. Yathirajan, H. S. Kubicki, Maciej Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal, the mol­ecules of the title compound, C(15)H(10)BrNO, are connected into centrosymmetric dimers by pairs of N—H⋯O hydrogen bonds. The dihedral angle between the planes of indole ring system and benzene ring is 50.13 (5)°. The indole plane is significantly less twisted from the plane of the central C—C(=O)—C bridge than the benzene plane [dihedral angles = 15.51 (3) and 40.13 (7)°, respectively]. The bond angles within the benzene ring show an approximately additive effect of the influence of both substituents. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971073/ /pubmed/21578509 http://dx.doi.org/10.1107/S1600536809040914 Text en © Dutkiewicz et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dutkiewicz, Grzegorz
Chidan Kumar, C. S.
Yathirajan, H. S.
Kubicki, Maciej
(4-Bromo­phen­yl)(1H-indol-7-yl)methanone
title (4-Bromo­phen­yl)(1H-indol-7-yl)methanone
title_full (4-Bromo­phen­yl)(1H-indol-7-yl)methanone
title_fullStr (4-Bromo­phen­yl)(1H-indol-7-yl)methanone
title_full_unstemmed (4-Bromo­phen­yl)(1H-indol-7-yl)methanone
title_short (4-Bromo­phen­yl)(1H-indol-7-yl)methanone
title_sort (4-bromo­phen­yl)(1h-indol-7-yl)methanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971073/
https://www.ncbi.nlm.nih.gov/pubmed/21578509
http://dx.doi.org/10.1107/S1600536809040914
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AT yathirajanhs 4bromophenyl1hindol7ylmethanone
AT kubickimaciej 4bromophenyl1hindol7ylmethanone

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