Diammonium diaqua­bis(methyl­enediphospho­nato-κ (2) O,O′)cobaltate(II)

In the salt, (NH(4))(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], the methyl­ene­diphospho­nate acts as a bidentate ligand and the Co(II) ion (site symmetry [Image: see text]) assumes an octa­hedral CoO(6) coordination geometry. The acid H atom of the ligand is distributed over two O atoms. In the crystal, a...

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Detalles Bibliográficos
Autores principales: Van der Merwe, K. A., Visser, Hendrik G., Venter, J. A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971074/
https://www.ncbi.nlm.nih.gov/pubmed/21578138
http://dx.doi.org/10.1107/S1600536809042159
Descripción
Sumario:In the salt, (NH(4))(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], the methyl­ene­diphospho­nate acts as a bidentate ligand and the Co(II) ion (site symmetry [Image: see text]) assumes an octa­hedral CoO(6) coordination geometry. The acid H atom of the ligand is distributed over two O atoms. In the crystal, a three-dimensional network is formed through O—H⋯O and N—H⋯O hydrogen bonds between the cations and anions.

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