Cargando…
Diammonium diaquabis(methylenediphosphonato-κ (2) O,O′)cobaltate(II)
In the salt, (NH(4))(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], the methylenediphosphonate acts as a bidentate ligand and the Co(II) ion (site symmetry [Image: see text]) assumes an octahedral CoO(6) coordination geometry. The acid H atom of the ligand is distributed over two O atoms. In the crystal, a...
| Autores principales: | , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971074/ https://www.ncbi.nlm.nih.gov/pubmed/21578138 http://dx.doi.org/10.1107/S1600536809042159 |
| _version_ | 1782190540217909248 |
|---|---|
| author | Van der Merwe, K. A. Visser, Hendrik G. Venter, J. A. |
| author_facet | Van der Merwe, K. A. Visser, Hendrik G. Venter, J. A. |
| author_sort | Van der Merwe, K. A. |
| collection | PubMed |
| description | In the salt, (NH(4))(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], the methylenediphosphonate acts as a bidentate ligand and the Co(II) ion (site symmetry [Image: see text]) assumes an octahedral CoO(6) coordination geometry. The acid H atom of the ligand is distributed over two O atoms. In the crystal, a three-dimensional network is formed through O—H⋯O and N—H⋯O hydrogen bonds between the cations and anions. |
| format | Text |
| id | pubmed-2971074 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29710742010-12-30 Diammonium diaquabis(methylenediphosphonato-κ (2) O,O′)cobaltate(II) Van der Merwe, K. A. Visser, Hendrik G. Venter, J. A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the salt, (NH(4))(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], the methylenediphosphonate acts as a bidentate ligand and the Co(II) ion (site symmetry [Image: see text]) assumes an octahedral CoO(6) coordination geometry. The acid H atom of the ligand is distributed over two O atoms. In the crystal, a three-dimensional network is formed through O—H⋯O and N—H⋯O hydrogen bonds between the cations and anions. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971074/ /pubmed/21578138 http://dx.doi.org/10.1107/S1600536809042159 Text en © Van der Merwe et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Van der Merwe, K. A. Visser, Hendrik G. Venter, J. A. Diammonium diaquabis(methylenediphosphonato-κ (2) O,O′)cobaltate(II) |
| title | Diammonium diaquabis(methylenediphosphonato-κ
(2)
O,O′)cobaltate(II) |
| title_full | Diammonium diaquabis(methylenediphosphonato-κ
(2)
O,O′)cobaltate(II) |
| title_fullStr | Diammonium diaquabis(methylenediphosphonato-κ
(2)
O,O′)cobaltate(II) |
| title_full_unstemmed | Diammonium diaquabis(methylenediphosphonato-κ
(2)
O,O′)cobaltate(II) |
| title_short | Diammonium diaquabis(methylenediphosphonato-κ
(2)
O,O′)cobaltate(II) |
| title_sort | diammonium diaquabis(methylenediphosphonato-κ
(2)
o,o′)cobaltate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971074/ https://www.ncbi.nlm.nih.gov/pubmed/21578138 http://dx.doi.org/10.1107/S1600536809042159 |
| work_keys_str_mv | AT vandermerweka diammoniumdiaquabismethylenediphosphonatok2oocobaltateii AT visserhendrikg diammoniumdiaquabismethylenediphosphonatok2oocobaltateii AT venterja diammoniumdiaquabismethylenediphosphonatok2oocobaltateii |