Phenyl 4-methyl­benzoate

The structure of the title compound, C(14)H(12)O(2), resembles those of phenyl benzoate and 4-methyl­phenyl benzoate, with similar bond parameters. The two aromatic rings make a dihedral angle of 76.0 (1)°. The plane of the central —C(=O)—O— group is twisted by 9.4 (2)° out of the plane of the benzo...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Tokarčík, Miroslav, Kožíšek, Jozef, Suchetan, P. A., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971075/
https://www.ncbi.nlm.nih.gov/pubmed/21578236
http://dx.doi.org/10.1107/S1600536809039361
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author Gowda, B. Thimme
Tokarčík, Miroslav
Kožíšek, Jozef
Suchetan, P. A.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Tokarčík, Miroslav
Kožíšek, Jozef
Suchetan, P. A.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description The structure of the title compound, C(14)H(12)O(2), resembles those of phenyl benzoate and 4-methyl­phenyl benzoate, with similar bond parameters. The two aromatic rings make a dihedral angle of 76.0 (1)°. The plane of the central —C(=O)—O— group is twisted by 9.4 (2)° out of the plane of the benzoyl ring, and by 83.3 (1)° out of the plane of the phenyl ring. The crystal structure exhibits weak parallel stacking of the benzoyl rings, with an inter­planar distance of 3.65 Å and an offset of 1.84 Å. The methyl group shows orientational disorder.
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spelling pubmed-29710752010-12-30 Phenyl 4-methyl­benzoate Gowda, B. Thimme Tokarčík, Miroslav Kožíšek, Jozef Suchetan, P. A. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers The structure of the title compound, C(14)H(12)O(2), resembles those of phenyl benzoate and 4-methyl­phenyl benzoate, with similar bond parameters. The two aromatic rings make a dihedral angle of 76.0 (1)°. The plane of the central —C(=O)—O— group is twisted by 9.4 (2)° out of the plane of the benzoyl ring, and by 83.3 (1)° out of the plane of the phenyl ring. The crystal structure exhibits weak parallel stacking of the benzoyl rings, with an inter­planar distance of 3.65 Å and an offset of 1.84 Å. The methyl group shows orientational disorder. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971075/ /pubmed/21578236 http://dx.doi.org/10.1107/S1600536809039361 Text en © Gowda et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Tokarčík, Miroslav
Kožíšek, Jozef
Suchetan, P. A.
Fuess, Hartmut
Phenyl 4-methyl­benzoate
title Phenyl 4-methyl­benzoate
title_full Phenyl 4-methyl­benzoate
title_fullStr Phenyl 4-methyl­benzoate
title_full_unstemmed Phenyl 4-methyl­benzoate
title_short Phenyl 4-methyl­benzoate
title_sort phenyl 4-methyl­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971075/
https://www.ncbi.nlm.nih.gov/pubmed/21578236
http://dx.doi.org/10.1107/S1600536809039361
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AT kozisekjozef phenyl4methylbenzoate
AT suchetanpa phenyl4methylbenzoate
AT fuesshartmut phenyl4methylbenzoate

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