1,3-Difluoro­benzene

The weak electrostatic and dispersive forces between C(δ+)—F(δ−) and H(δ+)—C(δ−) are at the borderline of the hydrogen-bond phenomenon and are poorly directional and further deformed in the presence of other dominant inter­actions, e.g. C—H⋯π. The title compound, C(6)H(4)F(2), Z′ = 2, forms one-dime...

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Detalles Bibliográficos
Autores principales: Kirchner, Michael T., Bläser, Dieter, Boese, Roland, Thakur, Tejender S., Desiraju, Gautam R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971077/
https://www.ncbi.nlm.nih.gov/pubmed/21578278
http://dx.doi.org/10.1107/S1600536809038987
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author Kirchner, Michael T.
Bläser, Dieter
Boese, Roland
Thakur, Tejender S.
Desiraju, Gautam R.
author_facet Kirchner, Michael T.
Bläser, Dieter
Boese, Roland
Thakur, Tejender S.
Desiraju, Gautam R.
author_sort Kirchner, Michael T.
collection PubMed
description The weak electrostatic and dispersive forces between C(δ+)—F(δ−) and H(δ+)—C(δ−) are at the borderline of the hydrogen-bond phenomenon and are poorly directional and further deformed in the presence of other dominant inter­actions, e.g. C—H⋯π. The title compound, C(6)H(4)F(2), Z′ = 2, forms one-dimensional tapes along two homodromic C—H⋯F hydrogen bonds. The one-dimensional tapes are connected into corrugated two-dimensional sheets by further bi- or trifrucated C—H⋯F hydrogen bonds. Packing in the third dimension is controlled by C—H⋯π inter­actions.
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spelling pubmed-29710772010-12-30 1,3-Difluoro­benzene Kirchner, Michael T. Bläser, Dieter Boese, Roland Thakur, Tejender S. Desiraju, Gautam R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The weak electrostatic and dispersive forces between C(δ+)—F(δ−) and H(δ+)—C(δ−) are at the borderline of the hydrogen-bond phenomenon and are poorly directional and further deformed in the presence of other dominant inter­actions, e.g. C—H⋯π. The title compound, C(6)H(4)F(2), Z′ = 2, forms one-dimensional tapes along two homodromic C—H⋯F hydrogen bonds. The one-dimensional tapes are connected into corrugated two-dimensional sheets by further bi- or trifrucated C—H⋯F hydrogen bonds. Packing in the third dimension is controlled by C—H⋯π inter­actions. International Union of Crystallography 2009-10-07 /pmc/articles/PMC2971077/ /pubmed/21578278 http://dx.doi.org/10.1107/S1600536809038987 Text en © Kirchner et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kirchner, Michael T.
Bläser, Dieter
Boese, Roland
Thakur, Tejender S.
Desiraju, Gautam R.
1,3-Difluoro­benzene
title 1,3-Difluoro­benzene
title_full 1,3-Difluoro­benzene
title_fullStr 1,3-Difluoro­benzene
title_full_unstemmed 1,3-Difluoro­benzene
title_short 1,3-Difluoro­benzene
title_sort 1,3-difluoro­benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971077/
https://www.ncbi.nlm.nih.gov/pubmed/21578278
http://dx.doi.org/10.1107/S1600536809038987
work_keys_str_mv AT kirchnermichaelt 13difluorobenzene
AT blaserdieter 13difluorobenzene
AT boeseroland 13difluorobenzene
AT thakurtejenders 13difluorobenzene
AT desirajugautamr 13difluorobenzene

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