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(2-Acetylphenolato)(2,2′-bipyridine)nitratocopper(II)
In the title compound, [Cu(C(8)H(7)O(2))(NO(3))(C(10)H(8)N(2))], the Cu(II) ion is five-coordinate in a distorted square-pyramidal geometry. The basal positions are occupied by two N atoms from a 2,2′-bipyridine ligand and two O atoms from the 2-acetylphenolate anion. The axial position is occupied...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971079/ https://www.ncbi.nlm.nih.gov/pubmed/21578163 http://dx.doi.org/10.1107/S1600536809042718 |
| _version_ | 1782190541364002816 |
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| author | Chen, Li-Hua Zhao, Gan-Qing Wang, Xiang Peng, Qin-Long Pan, Zi-Hong |
| author_facet | Chen, Li-Hua Zhao, Gan-Qing Wang, Xiang Peng, Qin-Long Pan, Zi-Hong |
| author_sort | Chen, Li-Hua |
| collection | PubMed |
| description | In the title compound, [Cu(C(8)H(7)O(2))(NO(3))(C(10)H(8)N(2))], the Cu(II) ion is five-coordinate in a distorted square-pyramidal geometry. The basal positions are occupied by two N atoms from a 2,2′-bipyridine ligand and two O atoms from the 2-acetylphenolate anion. The axial position is occupied by one O atom of a nitrate anion. In the bipyridine ligand, the two pyridine rings are slightly twisted by an angle of 3.5 (1)°. The crystal structure is stabilized by C—H⋯O hydrogen bonds |
| format | Text |
| id | pubmed-2971079 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29710792010-12-30 (2-Acetylphenolato)(2,2′-bipyridine)nitratocopper(II) Chen, Li-Hua Zhao, Gan-Qing Wang, Xiang Peng, Qin-Long Pan, Zi-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(8)H(7)O(2))(NO(3))(C(10)H(8)N(2))], the Cu(II) ion is five-coordinate in a distorted square-pyramidal geometry. The basal positions are occupied by two N atoms from a 2,2′-bipyridine ligand and two O atoms from the 2-acetylphenolate anion. The axial position is occupied by one O atom of a nitrate anion. In the bipyridine ligand, the two pyridine rings are slightly twisted by an angle of 3.5 (1)°. The crystal structure is stabilized by C—H⋯O hydrogen bonds International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971079/ /pubmed/21578163 http://dx.doi.org/10.1107/S1600536809042718 Text en © Chen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chen, Li-Hua Zhao, Gan-Qing Wang, Xiang Peng, Qin-Long Pan, Zi-Hong (2-Acetylphenolato)(2,2′-bipyridine)nitratocopper(II) |
| title | (2-Acetylphenolato)(2,2′-bipyridine)nitratocopper(II) |
| title_full | (2-Acetylphenolato)(2,2′-bipyridine)nitratocopper(II) |
| title_fullStr | (2-Acetylphenolato)(2,2′-bipyridine)nitratocopper(II) |
| title_full_unstemmed | (2-Acetylphenolato)(2,2′-bipyridine)nitratocopper(II) |
| title_short | (2-Acetylphenolato)(2,2′-bipyridine)nitratocopper(II) |
| title_sort | (2-acetylphenolato)(2,2′-bipyridine)nitratocopper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971079/ https://www.ncbi.nlm.nih.gov/pubmed/21578163 http://dx.doi.org/10.1107/S1600536809042718 |
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