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Di-μ-chlorido-bis[(2′-carboxybiphenyl-2-carboxylato-κO)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)] hemihydrate
In the centrosymmetric dinuclear title compound, [Cd(2)(C(14)H(9)O(4))(2)Cl(2)(C(15)H(11)N(3))(2)]·0.5H(2)O, each of the Cd(II) ions is coordinated by three N atoms from a chelating 2,2′:6′,2′′-terpyridine ligand, two bridging Cl atoms and one O atom of a 2′-carboxy-[1,1′-biphenyl]-2-carboxylate...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971083/ https://www.ncbi.nlm.nih.gov/pubmed/21578148 http://dx.doi.org/10.1107/S1600536809042044 |
Sumario: | In the centrosymmetric dinuclear title compound, [Cd(2)(C(14)H(9)O(4))(2)Cl(2)(C(15)H(11)N(3))(2)]·0.5H(2)O, each of the Cd(II) ions is coordinated by three N atoms from a chelating 2,2′:6′,2′′-terpyridine ligand, two bridging Cl atoms and one O atom of a 2′-carboxy-[1,1′-biphenyl]-2-carboxylate anion. The coordination environment is distorted octahedral. In the crystal, intermolecular O—H⋯O hydrogen bonds link symmetry-related molecules, forming an infinite chain. The half-occupancy water molecule is disordered over two general sites with 0.25 occupancy and is, in turn, disordered over an inversion center. |
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