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Di-μ-chlorido-bis[(2′-carboxybiphenyl-2-carboxylato-κO)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)] hemihydrate
In the centrosymmetric dinuclear title compound, [Cd(2)(C(14)H(9)O(4))(2)Cl(2)(C(15)H(11)N(3))(2)]·0.5H(2)O, each of the Cd(II) ions is coordinated by three N atoms from a chelating 2,2′:6′,2′′-terpyridine ligand, two bridging Cl atoms and one O atom of a 2′-carboxy-[1,1′-biphenyl]-2-carboxylate...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971083/ https://www.ncbi.nlm.nih.gov/pubmed/21578148 http://dx.doi.org/10.1107/S1600536809042044 |
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author | Zhang, Wu Li, Wen-Juan |
author_facet | Zhang, Wu Li, Wen-Juan |
author_sort | Zhang, Wu |
collection | PubMed |
description | In the centrosymmetric dinuclear title compound, [Cd(2)(C(14)H(9)O(4))(2)Cl(2)(C(15)H(11)N(3))(2)]·0.5H(2)O, each of the Cd(II) ions is coordinated by three N atoms from a chelating 2,2′:6′,2′′-terpyridine ligand, two bridging Cl atoms and one O atom of a 2′-carboxy-[1,1′-biphenyl]-2-carboxylate anion. The coordination environment is distorted octahedral. In the crystal, intermolecular O—H⋯O hydrogen bonds link symmetry-related molecules, forming an infinite chain. The half-occupancy water molecule is disordered over two general sites with 0.25 occupancy and is, in turn, disordered over an inversion center. |
format | Text |
id | pubmed-2971083 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29710832010-12-30 Di-μ-chlorido-bis[(2′-carboxybiphenyl-2-carboxylato-κO)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)] hemihydrate Zhang, Wu Li, Wen-Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title compound, [Cd(2)(C(14)H(9)O(4))(2)Cl(2)(C(15)H(11)N(3))(2)]·0.5H(2)O, each of the Cd(II) ions is coordinated by three N atoms from a chelating 2,2′:6′,2′′-terpyridine ligand, two bridging Cl atoms and one O atom of a 2′-carboxy-[1,1′-biphenyl]-2-carboxylate anion. The coordination environment is distorted octahedral. In the crystal, intermolecular O—H⋯O hydrogen bonds link symmetry-related molecules, forming an infinite chain. The half-occupancy water molecule is disordered over two general sites with 0.25 occupancy and is, in turn, disordered over an inversion center. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971083/ /pubmed/21578148 http://dx.doi.org/10.1107/S1600536809042044 Text en © Zhang and Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Wu Li, Wen-Juan Di-μ-chlorido-bis[(2′-carboxybiphenyl-2-carboxylato-κO)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)] hemihydrate |
title | Di-μ-chlorido-bis[(2′-carboxybiphenyl-2-carboxylato-κO)(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)cadmium(II)] hemihydrate |
title_full | Di-μ-chlorido-bis[(2′-carboxybiphenyl-2-carboxylato-κO)(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)cadmium(II)] hemihydrate |
title_fullStr | Di-μ-chlorido-bis[(2′-carboxybiphenyl-2-carboxylato-κO)(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)cadmium(II)] hemihydrate |
title_full_unstemmed | Di-μ-chlorido-bis[(2′-carboxybiphenyl-2-carboxylato-κO)(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)cadmium(II)] hemihydrate |
title_short | Di-μ-chlorido-bis[(2′-carboxybiphenyl-2-carboxylato-κO)(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)cadmium(II)] hemihydrate |
title_sort | di-μ-chlorido-bis[(2′-carboxybiphenyl-2-carboxylato-κo)(2,2′:6′,2′′-terpyridine-κ(3)
n,n′,n′′)cadmium(ii)] hemihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971083/ https://www.ncbi.nlm.nih.gov/pubmed/21578148 http://dx.doi.org/10.1107/S1600536809042044 |
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