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Di-μ-chlorido-bis­[(2′-carb­oxybiphen­yl-2-carboxyl­ato-κO)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)] hemihydrate

In the centrosymmetric dinuclear title compound, [Cd(2)(C(14)H(9)O(4))(2)Cl(2)(C(15)H(11)N(3))(2)]·0.5H(2)O, each of the Cd(II) ions is coordinated by three N atoms from a chelating 2,2′:6′,2′′-terpyridine ligand, two bridging Cl atoms and one O atom of a 2′-carb­oxy-[1,1′-biphen­yl]-2-carboxyl­ate...

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Detalles Bibliográficos
Autores principales: Zhang, Wu, Li, Wen-Juan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971083/
https://www.ncbi.nlm.nih.gov/pubmed/21578148
http://dx.doi.org/10.1107/S1600536809042044
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author Zhang, Wu
Li, Wen-Juan
author_facet Zhang, Wu
Li, Wen-Juan
author_sort Zhang, Wu
collection PubMed
description In the centrosymmetric dinuclear title compound, [Cd(2)(C(14)H(9)O(4))(2)Cl(2)(C(15)H(11)N(3))(2)]·0.5H(2)O, each of the Cd(II) ions is coordinated by three N atoms from a chelating 2,2′:6′,2′′-terpyridine ligand, two bridging Cl atoms and one O atom of a 2′-carb­oxy-[1,1′-biphen­yl]-2-carboxyl­ate anion. The coordination environment is distorted octa­hedral. In the crystal, inter­molecular O—H⋯O hydrogen bonds link symmetry-related mol­ecules, forming an infinite chain. The half-occupancy water mol­ecule is disordered over two general sites with 0.25 occupancy and is, in turn, disordered over an inversion center.
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spelling pubmed-29710832010-12-30 Di-μ-chlorido-bis­[(2′-carb­oxybiphen­yl-2-carboxyl­ato-κO)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)] hemihydrate Zhang, Wu Li, Wen-Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title compound, [Cd(2)(C(14)H(9)O(4))(2)Cl(2)(C(15)H(11)N(3))(2)]·0.5H(2)O, each of the Cd(II) ions is coordinated by three N atoms from a chelating 2,2′:6′,2′′-terpyridine ligand, two bridging Cl atoms and one O atom of a 2′-carb­oxy-[1,1′-biphen­yl]-2-carboxyl­ate anion. The coordination environment is distorted octa­hedral. In the crystal, inter­molecular O—H⋯O hydrogen bonds link symmetry-related mol­ecules, forming an infinite chain. The half-occupancy water mol­ecule is disordered over two general sites with 0.25 occupancy and is, in turn, disordered over an inversion center. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971083/ /pubmed/21578148 http://dx.doi.org/10.1107/S1600536809042044 Text en © Zhang and Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Wu
Li, Wen-Juan
Di-μ-chlorido-bis­[(2′-carb­oxybiphen­yl-2-carboxyl­ato-κO)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)] hemihydrate
title Di-μ-chlorido-bis­[(2′-carb­oxybiphen­yl-2-carboxyl­ato-κO)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)] hemihydrate
title_full Di-μ-chlorido-bis­[(2′-carb­oxybiphen­yl-2-carboxyl­ato-κO)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)] hemihydrate
title_fullStr Di-μ-chlorido-bis­[(2′-carb­oxybiphen­yl-2-carboxyl­ato-κO)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)] hemihydrate
title_full_unstemmed Di-μ-chlorido-bis­[(2′-carb­oxybiphen­yl-2-carboxyl­ato-κO)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)] hemihydrate
title_short Di-μ-chlorido-bis­[(2′-carb­oxybiphen­yl-2-carboxyl­ato-κO)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)] hemihydrate
title_sort di-μ-chlorido-bis­[(2′-carb­oxybiphen­yl-2-carboxyl­ato-κo)(2,2′:6′,2′′-terpyridine-κ(3) n,n′,n′′)cadmium(ii)] hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971083/
https://www.ncbi.nlm.nih.gov/pubmed/21578148
http://dx.doi.org/10.1107/S1600536809042044
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AT liwenjuan dimchloridobis2carboxybiphenyl2carboxylatoko2262terpyridinek3nnncadmiumiihemihydrate