Dibromido(2,3,9,10-tetra­methyl-1,4,8,11-tetra­azacyclo­tetra­deca-1,3,8,10-tetra­ene)cobalt(III) bromide

In the title compound, [CoBr(2)(C(14)H(24)N(4))]·Br, the Co(III) ion is located on an inversion centre and possesses a distorted octa­hedral coordination geometry in which four nitro­gen donors of the ligand mol­ecule are in the equatorial plane and two Br(−) ions occupy both the axial sites to give...

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Autores principales: El-Ghamry, Hoda, Issa, Raafat, El-Baradie, Kamal, Masaoka, Shigeyuki, Sakai, Ken
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971086/
https://www.ncbi.nlm.nih.gov/pubmed/21578128
http://dx.doi.org/10.1107/S160053680904166X
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author El-Ghamry, Hoda
Issa, Raafat
El-Baradie, Kamal
Masaoka, Shigeyuki
Sakai, Ken
author_facet El-Ghamry, Hoda
Issa, Raafat
El-Baradie, Kamal
Masaoka, Shigeyuki
Sakai, Ken
author_sort El-Ghamry, Hoda
collection PubMed
description In the title compound, [CoBr(2)(C(14)H(24)N(4))]·Br, the Co(III) ion is located on an inversion centre and possesses a distorted octa­hedral coordination geometry in which four nitro­gen donors of the ligand mol­ecule are in the equatorial plane and two Br(−) ions occupy both the axial sites to give a trans isomer. The Br(- )counter- anion is also located on an inversion centre.
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spelling pubmed-29710862010-12-30 Dibromido(2,3,9,10-tetra­methyl-1,4,8,11-tetra­azacyclo­tetra­deca-1,3,8,10-tetra­ene)cobalt(III) bromide El-Ghamry, Hoda Issa, Raafat El-Baradie, Kamal Masaoka, Shigeyuki Sakai, Ken Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoBr(2)(C(14)H(24)N(4))]·Br, the Co(III) ion is located on an inversion centre and possesses a distorted octa­hedral coordination geometry in which four nitro­gen donors of the ligand mol­ecule are in the equatorial plane and two Br(−) ions occupy both the axial sites to give a trans isomer. The Br(- )counter- anion is also located on an inversion centre. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971086/ /pubmed/21578128 http://dx.doi.org/10.1107/S160053680904166X Text en © El-Ghamry et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
El-Ghamry, Hoda
Issa, Raafat
El-Baradie, Kamal
Masaoka, Shigeyuki
Sakai, Ken
Dibromido(2,3,9,10-tetra­methyl-1,4,8,11-tetra­azacyclo­tetra­deca-1,3,8,10-tetra­ene)cobalt(III) bromide
title Dibromido(2,3,9,10-tetra­methyl-1,4,8,11-tetra­azacyclo­tetra­deca-1,3,8,10-tetra­ene)cobalt(III) bromide
title_full Dibromido(2,3,9,10-tetra­methyl-1,4,8,11-tetra­azacyclo­tetra­deca-1,3,8,10-tetra­ene)cobalt(III) bromide
title_fullStr Dibromido(2,3,9,10-tetra­methyl-1,4,8,11-tetra­azacyclo­tetra­deca-1,3,8,10-tetra­ene)cobalt(III) bromide
title_full_unstemmed Dibromido(2,3,9,10-tetra­methyl-1,4,8,11-tetra­azacyclo­tetra­deca-1,3,8,10-tetra­ene)cobalt(III) bromide
title_short Dibromido(2,3,9,10-tetra­methyl-1,4,8,11-tetra­azacyclo­tetra­deca-1,3,8,10-tetra­ene)cobalt(III) bromide
title_sort dibromido(2,3,9,10-tetra­methyl-1,4,8,11-tetra­azacyclo­tetra­deca-1,3,8,10-tetra­ene)cobalt(iii) bromide
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971086/
https://www.ncbi.nlm.nih.gov/pubmed/21578128
http://dx.doi.org/10.1107/S160053680904166X
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AT elbaradiekamal dibromido23910tetramethyl14811tetraazacyclotetradeca13810tetraenecobaltiiibromide
AT masaokashigeyuki dibromido23910tetramethyl14811tetraazacyclotetradeca13810tetraenecobaltiiibromide
AT sakaiken dibromido23910tetramethyl14811tetraazacyclotetradeca13810tetraenecobaltiiibromide

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