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Tetrapotassium heptacyanidomolybdate(III) dihydrate
The asymmetric unit of the title compound, K(I) (4)[Mo(III)(CN)(7)]·2H(2)O, consists of one [Mo(CN)(7)](4−) anion, four K(+) cations, and two water molecules. The [Mo(III)(CN)(7)](4−) anion has a seven-coordinated capped-trigonal-prismatic coordination geometry. The site-occupancy factors of the di...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971091/ https://www.ncbi.nlm.nih.gov/pubmed/21578037 http://dx.doi.org/10.1107/S1600536809039336 |
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| author | Nakabayashi, Koji Tomono, Keisuke Tsunobuchi, Yoshihide Kosaka, Wataru Ohkoshi, Shin-ichi |
| author_facet | Nakabayashi, Koji Tomono, Keisuke Tsunobuchi, Yoshihide Kosaka, Wataru Ohkoshi, Shin-ichi |
| author_sort | Nakabayashi, Koji |
| collection | PubMed |
| description | The asymmetric unit of the title compound, K(I) (4)[Mo(III)(CN)(7)]·2H(2)O, consists of one [Mo(CN)(7)](4−) anion, four K(+) cations, and two water molecules. The [Mo(III)(CN)(7)](4−) anion has a seven-coordinated capped-trigonal-prismatic coordination geometry. The site-occupancy factors of the disordered water molecules were set at 0.90, 0.60 and 0.50. The H-atom positions could not be determined for two of the water molecules. The H atoms of the water with a site-occupancy factor of 0.90 were refined using O—H and H⋯H distance restraints. |
| format | Text |
| id | pubmed-2971091 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29710912010-12-30 Tetrapotassium heptacyanidomolybdate(III) dihydrate Nakabayashi, Koji Tomono, Keisuke Tsunobuchi, Yoshihide Kosaka, Wataru Ohkoshi, Shin-ichi Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The asymmetric unit of the title compound, K(I) (4)[Mo(III)(CN)(7)]·2H(2)O, consists of one [Mo(CN)(7)](4−) anion, four K(+) cations, and two water molecules. The [Mo(III)(CN)(7)](4−) anion has a seven-coordinated capped-trigonal-prismatic coordination geometry. The site-occupancy factors of the disordered water molecules were set at 0.90, 0.60 and 0.50. The H-atom positions could not be determined for two of the water molecules. The H atoms of the water with a site-occupancy factor of 0.90 were refined using O—H and H⋯H distance restraints. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971091/ /pubmed/21578037 http://dx.doi.org/10.1107/S1600536809039336 Text en © Nakabayashi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Inorganic Papers Nakabayashi, Koji Tomono, Keisuke Tsunobuchi, Yoshihide Kosaka, Wataru Ohkoshi, Shin-ichi Tetrapotassium heptacyanidomolybdate(III) dihydrate |
| title | Tetrapotassium heptacyanidomolybdate(III) dihydrate |
| title_full | Tetrapotassium heptacyanidomolybdate(III) dihydrate |
| title_fullStr | Tetrapotassium heptacyanidomolybdate(III) dihydrate |
| title_full_unstemmed | Tetrapotassium heptacyanidomolybdate(III) dihydrate |
| title_short | Tetrapotassium heptacyanidomolybdate(III) dihydrate |
| title_sort | tetrapotassium heptacyanidomolybdate(iii) dihydrate |
| topic | Inorganic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971091/ https://www.ncbi.nlm.nih.gov/pubmed/21578037 http://dx.doi.org/10.1107/S1600536809039336 |
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