5-(4,5-Diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis(methyl­sulfan­yl)-2,2′-bi-1,3-dithiol-4(5H)-one

The mol­ecular framework of the title compound, C(11)H(6)I(2)OS(8), is almost planar [maximum deviation = 0.057 (5) Å] except for the two methyl­sulfanyl groups, which are twisted relative to the mol­ecular skeleton, with C—C—S—C torsion angles of 49.74 (22) and 82.91 (21)°. In the crystal, mol­ecul...

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Detalles Bibliográficos
Autores principales: Ueda, Kazumasa, Yoza, Kenji
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971092/
https://www.ncbi.nlm.nih.gov/pubmed/21578314
http://dx.doi.org/10.1107/S160053680904032X
Descripción
Sumario:The mol­ecular framework of the title compound, C(11)H(6)I(2)OS(8), is almost planar [maximum deviation = 0.057 (5) Å] except for the two methyl­sulfanyl groups, which are twisted relative to the mol­ecular skeleton, with C—C—S—C torsion angles of 49.74 (22) and 82.91 (21)°. In the crystal, mol­ecules are stacked alternately in opposite orientations, forming a one-dimensional column along the b axis. The inter­action between adjacent columns is accomplished through S⋯S [3.4289 (5) Å], S⋯I [3.4498 (4) Å] and O⋯I [2.812 (2) Å] contacts.

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