5-(4,5-Diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis(methyl­sulfan­yl)-2,2′-bi-1,3-dithiol-4(5H)-one

The mol­ecular framework of the title compound, C(11)H(6)I(2)OS(8), is almost planar [maximum deviation = 0.057 (5) Å] except for the two methyl­sulfanyl groups, which are twisted relative to the mol­ecular skeleton, with C—C—S—C torsion angles of 49.74 (22) and 82.91 (21)°. In the crystal, mol­ecul...

Descripción completa

Detalles Bibliográficos
Autores principales: Ueda, Kazumasa, Yoza, Kenji
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971092/
https://www.ncbi.nlm.nih.gov/pubmed/21578314
http://dx.doi.org/10.1107/S160053680904032X
_version_ 1782190544387047424
author Ueda, Kazumasa
Yoza, Kenji
author_facet Ueda, Kazumasa
Yoza, Kenji
author_sort Ueda, Kazumasa
collection PubMed
description The mol­ecular framework of the title compound, C(11)H(6)I(2)OS(8), is almost planar [maximum deviation = 0.057 (5) Å] except for the two methyl­sulfanyl groups, which are twisted relative to the mol­ecular skeleton, with C—C—S—C torsion angles of 49.74 (22) and 82.91 (21)°. In the crystal, mol­ecules are stacked alternately in opposite orientations, forming a one-dimensional column along the b axis. The inter­action between adjacent columns is accomplished through S⋯S [3.4289 (5) Å], S⋯I [3.4498 (4) Å] and O⋯I [2.812 (2) Å] contacts.
format Text
id pubmed-2971092
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29710922010-12-30 5-(4,5-Diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis(methyl­sulfan­yl)-2,2′-bi-1,3-dithiol-4(5H)-one Ueda, Kazumasa Yoza, Kenji Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular framework of the title compound, C(11)H(6)I(2)OS(8), is almost planar [maximum deviation = 0.057 (5) Å] except for the two methyl­sulfanyl groups, which are twisted relative to the mol­ecular skeleton, with C—C—S—C torsion angles of 49.74 (22) and 82.91 (21)°. In the crystal, mol­ecules are stacked alternately in opposite orientations, forming a one-dimensional column along the b axis. The inter­action between adjacent columns is accomplished through S⋯S [3.4289 (5) Å], S⋯I [3.4498 (4) Å] and O⋯I [2.812 (2) Å] contacts. International Union of Crystallography 2009-10-10 /pmc/articles/PMC2971092/ /pubmed/21578314 http://dx.doi.org/10.1107/S160053680904032X Text en © Ueda and Yoza 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ueda, Kazumasa
Yoza, Kenji
5-(4,5-Diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis(methyl­sulfan­yl)-2,2′-bi-1,3-dithiol-4(5H)-one
title 5-(4,5-Diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis(methyl­sulfan­yl)-2,2′-bi-1,3-dithiol-4(5H)-one
title_full 5-(4,5-Diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis(methyl­sulfan­yl)-2,2′-bi-1,3-dithiol-4(5H)-one
title_fullStr 5-(4,5-Diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis(methyl­sulfan­yl)-2,2′-bi-1,3-dithiol-4(5H)-one
title_full_unstemmed 5-(4,5-Diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis(methyl­sulfan­yl)-2,2′-bi-1,3-dithiol-4(5H)-one
title_short 5-(4,5-Diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis(methyl­sulfan­yl)-2,2′-bi-1,3-dithiol-4(5H)-one
title_sort 5-(4,5-diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis(methyl­sulfan­yl)-2,2′-bi-1,3-dithiol-4(5h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971092/
https://www.ncbi.nlm.nih.gov/pubmed/21578314
http://dx.doi.org/10.1107/S160053680904032X
work_keys_str_mv AT uedakazumasa 545diiodo13dithiol2ylidene45bismethylsulfanyl22bi13dithiol45hone
AT yozakenji 545diiodo13dithiol2ylidene45bismethylsulfanyl22bi13dithiol45hone

Ejemplares similares