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Tetra-μ-benzoato-κ(8) O:O′-bis[(benzoic acid-κO)nickel(II)]
The title compound, [Ni(2)(C(7)H(5)O(2))(4)(C(7)H(6)O(2))(2)], is composed of two Ni(II) ions, four bridging benzoate anions and two η(1)-benzoic acid molecules. The [Ni(2)(PhCOO)(4)] unit adopts a typical paddle-wheel conformation. The center between the two Ni(II) atoms represents a crystallograp...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971096/ https://www.ncbi.nlm.nih.gov/pubmed/21578206 http://dx.doi.org/10.1107/S1600536809044766 |
| _version_ | 1782190545304551424 |
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| author | Deng, Ji-Hua Yi, Yan-Ping Xiong, Zhi-Xing Yuan, Lin Mei, Guang-Quan |
| author_facet | Deng, Ji-Hua Yi, Yan-Ping Xiong, Zhi-Xing Yuan, Lin Mei, Guang-Quan |
| author_sort | Deng, Ji-Hua |
| collection | PubMed |
| description | The title compound, [Ni(2)(C(7)H(5)O(2))(4)(C(7)H(6)O(2))(2)], is composed of two Ni(II) ions, four bridging benzoate anions and two η(1)-benzoic acid molecules. The [Ni(2)(PhCOO)(4)] unit adopts a typical paddle-wheel conformation. The center between the two Ni(II) atoms represents a crystallographic center of inversion. In addition, each Ni(II) ion also coordinates to one O atom from a benzoic acid molecule. The crystal packing is realised by intermolecular hydrogen-bonding interactions and π–π stacking interactions, with a centroid–centroid distance of 3.921 (1) Å. |
| format | Text |
| id | pubmed-2971096 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29710962010-12-30 Tetra-μ-benzoato-κ(8) O:O′-bis[(benzoic acid-κO)nickel(II)] Deng, Ji-Hua Yi, Yan-Ping Xiong, Zhi-Xing Yuan, Lin Mei, Guang-Quan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(2)(C(7)H(5)O(2))(4)(C(7)H(6)O(2))(2)], is composed of two Ni(II) ions, four bridging benzoate anions and two η(1)-benzoic acid molecules. The [Ni(2)(PhCOO)(4)] unit adopts a typical paddle-wheel conformation. The center between the two Ni(II) atoms represents a crystallographic center of inversion. In addition, each Ni(II) ion also coordinates to one O atom from a benzoic acid molecule. The crystal packing is realised by intermolecular hydrogen-bonding interactions and π–π stacking interactions, with a centroid–centroid distance of 3.921 (1) Å. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971096/ /pubmed/21578206 http://dx.doi.org/10.1107/S1600536809044766 Text en © Deng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Deng, Ji-Hua Yi, Yan-Ping Xiong, Zhi-Xing Yuan, Lin Mei, Guang-Quan Tetra-μ-benzoato-κ(8) O:O′-bis[(benzoic acid-κO)nickel(II)] |
| title | Tetra-μ-benzoato-κ(8)
O:O′-bis[(benzoic acid-κO)nickel(II)] |
| title_full | Tetra-μ-benzoato-κ(8)
O:O′-bis[(benzoic acid-κO)nickel(II)] |
| title_fullStr | Tetra-μ-benzoato-κ(8)
O:O′-bis[(benzoic acid-κO)nickel(II)] |
| title_full_unstemmed | Tetra-μ-benzoato-κ(8)
O:O′-bis[(benzoic acid-κO)nickel(II)] |
| title_short | Tetra-μ-benzoato-κ(8)
O:O′-bis[(benzoic acid-κO)nickel(II)] |
| title_sort | tetra-μ-benzoato-κ(8)
o:o′-bis[(benzoic acid-κo)nickel(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971096/ https://www.ncbi.nlm.nih.gov/pubmed/21578206 http://dx.doi.org/10.1107/S1600536809044766 |
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