Bis{[1-(tert-butoxy­carbonyl)­pyrrolidin-2-yl]meth­yl} carbonate

The asymmetric unit of the title compound, C(21)H(36)N(2)O(7), consists of two independent half-mol­ecules, the other halves being generated by twofold rotational axes. The two independent half-mol­ecules are related by a pseudo-inversion center. In one, the pyrrolidine ring adopts a twist conformat...

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Detalles Bibliográficos
Autor principal: Jing, Lin-Hai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971100/
https://www.ncbi.nlm.nih.gov/pubmed/21578227
http://dx.doi.org/10.1107/S1600536809039452
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author Jing, Lin-Hai
author_facet Jing, Lin-Hai
author_sort Jing, Lin-Hai
collection PubMed
description The asymmetric unit of the title compound, C(21)H(36)N(2)O(7), consists of two independent half-mol­ecules, the other halves being generated by twofold rotational axes. The two independent half-mol­ecules are related by a pseudo-inversion center. In one, the pyrrolidine ring adopts a twist conformation whereas in the other it is in an envelope conformation. The crystal packing is stabilized by C—H⋯O hydrogen bonds.
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spelling pubmed-29711002010-12-30 Bis{[1-(tert-butoxy­carbonyl)­pyrrolidin-2-yl]meth­yl} carbonate Jing, Lin-Hai Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(21)H(36)N(2)O(7), consists of two independent half-mol­ecules, the other halves being generated by twofold rotational axes. The two independent half-mol­ecules are related by a pseudo-inversion center. In one, the pyrrolidine ring adopts a twist conformation whereas in the other it is in an envelope conformation. The crystal packing is stabilized by C—H⋯O hydrogen bonds. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971100/ /pubmed/21578227 http://dx.doi.org/10.1107/S1600536809039452 Text en © Lin-Hai Jing 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jing, Lin-Hai
Bis{[1-(tert-butoxy­carbonyl)­pyrrolidin-2-yl]meth­yl} carbonate
title Bis{[1-(tert-butoxy­carbonyl)­pyrrolidin-2-yl]meth­yl} carbonate
title_full Bis{[1-(tert-butoxy­carbonyl)­pyrrolidin-2-yl]meth­yl} carbonate
title_fullStr Bis{[1-(tert-butoxy­carbonyl)­pyrrolidin-2-yl]meth­yl} carbonate
title_full_unstemmed Bis{[1-(tert-butoxy­carbonyl)­pyrrolidin-2-yl]meth­yl} carbonate
title_short Bis{[1-(tert-butoxy­carbonyl)­pyrrolidin-2-yl]meth­yl} carbonate
title_sort bis{[1-(tert-butoxy­carbonyl)­pyrrolidin-2-yl]meth­yl} carbonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971100/
https://www.ncbi.nlm.nih.gov/pubmed/21578227
http://dx.doi.org/10.1107/S1600536809039452
work_keys_str_mv AT jinglinhai bis1tertbutoxycarbonylpyrrolidin2ylmethylcarbonate

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