Bis[4′-(4-cyano­phen­yl)-2,2′:6′,2′′-terpyridine]cobalt(II) dichloride

The title complex, [Co(C(22)H(14)N(4))(2)]Cl(2), has been synthesized by a solvothermal reaction of the 4′-(4-cyano­phen­yl)-2,2′:6′,2′′-terpyridine ligand with CoCl(2)·6H(2)O. The cobalt(II) ion is six-coordinated by two tridentate ligands in a distorted octa­hedral geometry. The benzene rings form...

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Detalles Bibliográficos
Autores principales: Qian, Kun, Yan, Zhi-Hong, Chen, Zhong-Wen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971102/
https://www.ncbi.nlm.nih.gov/pubmed/21578106
http://dx.doi.org/10.1107/S160053680904046X
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author Qian, Kun
Yan, Zhi-Hong
Chen, Zhong-Wen
author_facet Qian, Kun
Yan, Zhi-Hong
Chen, Zhong-Wen
author_sort Qian, Kun
collection PubMed
description The title complex, [Co(C(22)H(14)N(4))(2)]Cl(2), has been synthesized by a solvothermal reaction of the 4′-(4-cyano­phen­yl)-2,2′:6′,2′′-terpyridine ligand with CoCl(2)·6H(2)O. The cobalt(II) ion is six-coordinated by two tridentate ligands in a distorted octa­hedral geometry. The benzene rings form dihedral angles of 30.02 (7) and 30.26 (7)° with the mean planes of the terpyridine ring systems. The chloride anions are statistically disordered over two positions with refined site occupancies of 0.601 (2) and 0.399 (2).
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spelling pubmed-29711022010-12-30 Bis[4′-(4-cyano­phen­yl)-2,2′:6′,2′′-terpyridine]cobalt(II) dichloride Qian, Kun Yan, Zhi-Hong Chen, Zhong-Wen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Co(C(22)H(14)N(4))(2)]Cl(2), has been synthesized by a solvothermal reaction of the 4′-(4-cyano­phen­yl)-2,2′:6′,2′′-terpyridine ligand with CoCl(2)·6H(2)O. The cobalt(II) ion is six-coordinated by two tridentate ligands in a distorted octa­hedral geometry. The benzene rings form dihedral angles of 30.02 (7) and 30.26 (7)° with the mean planes of the terpyridine ring systems. The chloride anions are statistically disordered over two positions with refined site occupancies of 0.601 (2) and 0.399 (2). International Union of Crystallography 2009-10-13 /pmc/articles/PMC2971102/ /pubmed/21578106 http://dx.doi.org/10.1107/S160053680904046X Text en © Qian et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Qian, Kun
Yan, Zhi-Hong
Chen, Zhong-Wen
Bis[4′-(4-cyano­phen­yl)-2,2′:6′,2′′-terpyridine]cobalt(II) dichloride
title Bis[4′-(4-cyano­phen­yl)-2,2′:6′,2′′-terpyridine]cobalt(II) dichloride
title_full Bis[4′-(4-cyano­phen­yl)-2,2′:6′,2′′-terpyridine]cobalt(II) dichloride
title_fullStr Bis[4′-(4-cyano­phen­yl)-2,2′:6′,2′′-terpyridine]cobalt(II) dichloride
title_full_unstemmed Bis[4′-(4-cyano­phen­yl)-2,2′:6′,2′′-terpyridine]cobalt(II) dichloride
title_short Bis[4′-(4-cyano­phen­yl)-2,2′:6′,2′′-terpyridine]cobalt(II) dichloride
title_sort bis[4′-(4-cyano­phen­yl)-2,2′:6′,2′′-terpyridine]cobalt(ii) dichloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971102/
https://www.ncbi.nlm.nih.gov/pubmed/21578106
http://dx.doi.org/10.1107/S160053680904046X
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AT yanzhihong bis44cyanophenyl2262terpyridinecobaltiidichloride
AT chenzhongwen bis44cyanophenyl2262terpyridinecobaltiidichloride

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