Dimeth­yl(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)

The title compound, [Zn(CH(3))(2)(C(15)H(11)N(3))], was synthesized by the addition of dimethyl­zinc to 2,2′:6′,2′′-terpyridine and was crystallized by the slow evaporation of THF. The penta­coordinate Zn(II) atom, lying on a twofold rotation axis, displays a distorted trigonal-bipyramidal geometry,...

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Detalles Bibliográficos
Autores principales: Shalumova, Tamila, Tanski, Joseph M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971104/
https://www.ncbi.nlm.nih.gov/pubmed/21578086
http://dx.doi.org/10.1107/S1600536809040136
Descripción
Sumario:The title compound, [Zn(CH(3))(2)(C(15)H(11)N(3))], was synthesized by the addition of dimethyl­zinc to 2,2′:6′,2′′-terpyridine and was crystallized by the slow evaporation of THF. The penta­coordinate Zn(II) atom, lying on a twofold rotation axis, displays a distorted trigonal-bipyramidal geometry, with two terminal N atoms at the axial positions and the central N atom and two methyl C atoms at the equatorial positions.

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