Dimeth­yl(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)

The title compound, [Zn(CH(3))(2)(C(15)H(11)N(3))], was synthesized by the addition of dimethyl­zinc to 2,2′:6′,2′′-terpyridine and was crystallized by the slow evaporation of THF. The penta­coordinate Zn(II) atom, lying on a twofold rotation axis, displays a distorted trigonal-bipyramidal geometry,...

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Detalles Bibliográficos
Autores principales: Shalumova, Tamila, Tanski, Joseph M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971104/
https://www.ncbi.nlm.nih.gov/pubmed/21578086
http://dx.doi.org/10.1107/S1600536809040136
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author Shalumova, Tamila
Tanski, Joseph M.
author_facet Shalumova, Tamila
Tanski, Joseph M.
author_sort Shalumova, Tamila
collection PubMed
description The title compound, [Zn(CH(3))(2)(C(15)H(11)N(3))], was synthesized by the addition of dimethyl­zinc to 2,2′:6′,2′′-terpyridine and was crystallized by the slow evaporation of THF. The penta­coordinate Zn(II) atom, lying on a twofold rotation axis, displays a distorted trigonal-bipyramidal geometry, with two terminal N atoms at the axial positions and the central N atom and two methyl C atoms at the equatorial positions.
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spelling pubmed-29711042010-12-30 Dimeth­yl(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II) Shalumova, Tamila Tanski, Joseph M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(CH(3))(2)(C(15)H(11)N(3))], was synthesized by the addition of dimethyl­zinc to 2,2′:6′,2′′-terpyridine and was crystallized by the slow evaporation of THF. The penta­coordinate Zn(II) atom, lying on a twofold rotation axis, displays a distorted trigonal-bipyramidal geometry, with two terminal N atoms at the axial positions and the central N atom and two methyl C atoms at the equatorial positions. International Union of Crystallography 2009-10-07 /pmc/articles/PMC2971104/ /pubmed/21578086 http://dx.doi.org/10.1107/S1600536809040136 Text en © Shalumova and Tanski 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shalumova, Tamila
Tanski, Joseph M.
Dimeth­yl(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)
title Dimeth­yl(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)
title_full Dimeth­yl(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)
title_fullStr Dimeth­yl(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)
title_full_unstemmed Dimeth­yl(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)
title_short Dimeth­yl(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)
title_sort dimeth­yl(2,2′:6′,2′′-terpyridine-κ(3) n,n′,n′′)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971104/
https://www.ncbi.nlm.nih.gov/pubmed/21578086
http://dx.doi.org/10.1107/S1600536809040136
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