Aqua{5,5′-dimethoxy-2,2-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)

The title mononuclear nickel(II) complex, [Ni(C(18)H(18)N(2)O(4))(H(2)O)], possesses crystallographic mirror symmetry. The Ni atom is five-coordinated in a square-pyramidal geometry, with two imine N and two phenolate O atoms of the Schiff base ligand in the square plane, and the water O atom in the...

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Detalles Bibliográficos
Autor principal: Tang, Chunbao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971105/
https://www.ncbi.nlm.nih.gov/pubmed/21578049
http://dx.doi.org/10.1107/S1600536809039129
Descripción
Sumario:The title mononuclear nickel(II) complex, [Ni(C(18)H(18)N(2)O(4))(H(2)O)], possesses crystallographic mirror symmetry. The Ni atom is five-coordinated in a square-pyramidal geometry, with two imine N and two phenolate O atoms of the Schiff base ligand in the square plane, and the water O atom in the axial position. In the crystal, the mol­ecules are linked via inter­molecular O—H⋯O hydrogen bonds, forming chains along the a axis.

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