Aqua{5,5′-dimethoxy-2,2-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)

The title mononuclear nickel(II) complex, [Ni(C(18)H(18)N(2)O(4))(H(2)O)], possesses crystallographic mirror symmetry. The Ni atom is five-coordinated in a square-pyramidal geometry, with two imine N and two phenolate O atoms of the Schiff base ligand in the square plane, and the water O atom in the...

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Detalles Bibliográficos
Autor principal: Tang, Chunbao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971105/
https://www.ncbi.nlm.nih.gov/pubmed/21578049
http://dx.doi.org/10.1107/S1600536809039129
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author Tang, Chunbao
author_facet Tang, Chunbao
author_sort Tang, Chunbao
collection PubMed
description The title mononuclear nickel(II) complex, [Ni(C(18)H(18)N(2)O(4))(H(2)O)], possesses crystallographic mirror symmetry. The Ni atom is five-coordinated in a square-pyramidal geometry, with two imine N and two phenolate O atoms of the Schiff base ligand in the square plane, and the water O atom in the axial position. In the crystal, the mol­ecules are linked via inter­molecular O—H⋯O hydrogen bonds, forming chains along the a axis.
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spelling pubmed-29711052010-12-30 Aqua{5,5′-dimethoxy-2,2-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II) Tang, Chunbao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mononuclear nickel(II) complex, [Ni(C(18)H(18)N(2)O(4))(H(2)O)], possesses crystallographic mirror symmetry. The Ni atom is five-coordinated in a square-pyramidal geometry, with two imine N and two phenolate O atoms of the Schiff base ligand in the square plane, and the water O atom in the axial position. In the crystal, the mol­ecules are linked via inter­molecular O—H⋯O hydrogen bonds, forming chains along the a axis. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971105/ /pubmed/21578049 http://dx.doi.org/10.1107/S1600536809039129 Text en © Chunbao Tang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tang, Chunbao
Aqua{5,5′-dimethoxy-2,2-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)
title Aqua{5,5′-dimethoxy-2,2-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)
title_full Aqua{5,5′-dimethoxy-2,2-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)
title_fullStr Aqua{5,5′-dimethoxy-2,2-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)
title_full_unstemmed Aqua{5,5′-dimethoxy-2,2-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)
title_short Aqua{5,5′-dimethoxy-2,2-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)
title_sort aqua{5,5′-dimethoxy-2,2-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971105/
https://www.ncbi.nlm.nih.gov/pubmed/21578049
http://dx.doi.org/10.1107/S1600536809039129
work_keys_str_mv AT tangchunbao aqua55dimethoxy22ethane12diylbisnitrilomethylidynediphenolatonickelii

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