N-(4-Methoxy­phen­yl)-tert-butane­sulfinamide

In the title compound, C(11)H(17)NO(2)S, the mol­ecules inter­act head-to-tail through N—H⋯OS hydrogen bonds, giving discrete centrosymmetric cyclic dimers. The N—C(ar­yl) bond length [1.4225 (14) Å] is inter­mediate between that in N-phenyl-tert-butane­sulfinamide [1.4083 (12) Å] and the N—C(alk­yl...

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Detalles Bibliográficos
Autores principales: Datta, Mrityunjoy, Buglass, Alan J., Elsegood, Mark R. J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971111/
https://www.ncbi.nlm.nih.gov/pubmed/21578414
http://dx.doi.org/10.1107/S1600536809042548
Descripción
Sumario:In the title compound, C(11)H(17)NO(2)S, the mol­ecules inter­act head-to-tail through N—H⋯OS hydrogen bonds, giving discrete centrosymmetric cyclic dimers. The N—C(ar­yl) bond length [1.4225 (14) Å] is inter­mediate between that in N-phenyl-tert-butane­sulfinamide [1.4083 (12) Å] and the N—C(alk­yl) bond lengths in N-alkyl­alkanesulfinamides (1.470–1.530 Å), suggesting weaker delocalization of electrons over the N atom and the aromatic ring due to the presence of the 4-meth­oxy group.

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