N-(4-Methoxy­phen­yl)-tert-butane­sulfinamide

In the title compound, C(11)H(17)NO(2)S, the mol­ecules inter­act head-to-tail through N—H⋯OS hydrogen bonds, giving discrete centrosymmetric cyclic dimers. The N—C(ar­yl) bond length [1.4225 (14) Å] is inter­mediate between that in N-phenyl-tert-butane­sulfinamide [1.4083 (12) Å] and the N—C(alk­yl...

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Detalles Bibliográficos
Autores principales: Datta, Mrityunjoy, Buglass, Alan J., Elsegood, Mark R. J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971111/
https://www.ncbi.nlm.nih.gov/pubmed/21578414
http://dx.doi.org/10.1107/S1600536809042548
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author Datta, Mrityunjoy
Buglass, Alan J.
Elsegood, Mark R. J.
author_facet Datta, Mrityunjoy
Buglass, Alan J.
Elsegood, Mark R. J.
author_sort Datta, Mrityunjoy
collection PubMed
description In the title compound, C(11)H(17)NO(2)S, the mol­ecules inter­act head-to-tail through N—H⋯OS hydrogen bonds, giving discrete centrosymmetric cyclic dimers. The N—C(ar­yl) bond length [1.4225 (14) Å] is inter­mediate between that in N-phenyl-tert-butane­sulfinamide [1.4083 (12) Å] and the N—C(alk­yl) bond lengths in N-alkyl­alkanesulfinamides (1.470–1.530 Å), suggesting weaker delocalization of electrons over the N atom and the aromatic ring due to the presence of the 4-meth­oxy group.
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spelling pubmed-29711112010-12-30 N-(4-Methoxy­phen­yl)-tert-butane­sulfinamide Datta, Mrityunjoy Buglass, Alan J. Elsegood, Mark R. J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(17)NO(2)S, the mol­ecules inter­act head-to-tail through N—H⋯OS hydrogen bonds, giving discrete centrosymmetric cyclic dimers. The N—C(ar­yl) bond length [1.4225 (14) Å] is inter­mediate between that in N-phenyl-tert-butane­sulfinamide [1.4083 (12) Å] and the N—C(alk­yl) bond lengths in N-alkyl­alkanesulfinamides (1.470–1.530 Å), suggesting weaker delocalization of electrons over the N atom and the aromatic ring due to the presence of the 4-meth­oxy group. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971111/ /pubmed/21578414 http://dx.doi.org/10.1107/S1600536809042548 Text en © Datta et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Datta, Mrityunjoy
Buglass, Alan J.
Elsegood, Mark R. J.
N-(4-Methoxy­phen­yl)-tert-butane­sulfinamide
title N-(4-Methoxy­phen­yl)-tert-butane­sulfinamide
title_full N-(4-Methoxy­phen­yl)-tert-butane­sulfinamide
title_fullStr N-(4-Methoxy­phen­yl)-tert-butane­sulfinamide
title_full_unstemmed N-(4-Methoxy­phen­yl)-tert-butane­sulfinamide
title_short N-(4-Methoxy­phen­yl)-tert-butane­sulfinamide
title_sort n-(4-methoxy­phen­yl)-tert-butane­sulfinamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971111/
https://www.ncbi.nlm.nih.gov/pubmed/21578414
http://dx.doi.org/10.1107/S1600536809042548
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AT buglassalanj n4methoxyphenyltertbutanesulfinamide
AT elsegoodmarkrj n4methoxyphenyltertbutanesulfinamide

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