1-Formyl-r-2,c-6-bis­(4-methoxy­phen­yl)-t-3,t-5-dimethyl­piperidin-4-one

In the title compound, C(22)H(25)NO(4), the piperidine ring adopts a distorted boat conformation. The methyl groups at the 3 and 5 positions of the piperidine ring are in axial and equatorial orientations, respectively. Both H and O atoms in the aldehyde group are disordered over two positions with...

Descripción completa

Detalles Bibliográficos
Autores principales: Kavitha, T., Sakthivel, P., Ponnuswamy, S., Ilango, S. S., Ponnuswamy, M. N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971115/
https://www.ncbi.nlm.nih.gov/pubmed/21578409
http://dx.doi.org/10.1107/S1600536809041609
_version_ 1782190549773582336
author Kavitha, T.
Sakthivel, P.
Ponnuswamy, S.
Ilango, S. S.
Ponnuswamy, M. N.
author_facet Kavitha, T.
Sakthivel, P.
Ponnuswamy, S.
Ilango, S. S.
Ponnuswamy, M. N.
author_sort Kavitha, T.
collection PubMed
description In the title compound, C(22)H(25)NO(4), the piperidine ring adopts a distorted boat conformation. The methyl groups at the 3 and 5 positions of the piperidine ring are in axial and equatorial orientations, respectively. Both H and O atoms in the aldehyde group are disordered over two positions with occupancies of 0.534 (5) and 0.466 (5). In the crystal, the mol­ecules are linked into a three-dimensional network by C—H⋯O hydrogen bonds.
format Text
id pubmed-2971115
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29711152010-12-30 1-Formyl-r-2,c-6-bis­(4-methoxy­phen­yl)-t-3,t-5-dimethyl­piperidin-4-one Kavitha, T. Sakthivel, P. Ponnuswamy, S. Ilango, S. S. Ponnuswamy, M. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(25)NO(4), the piperidine ring adopts a distorted boat conformation. The methyl groups at the 3 and 5 positions of the piperidine ring are in axial and equatorial orientations, respectively. Both H and O atoms in the aldehyde group are disordered over two positions with occupancies of 0.534 (5) and 0.466 (5). In the crystal, the mol­ecules are linked into a three-dimensional network by C—H⋯O hydrogen bonds. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971115/ /pubmed/21578409 http://dx.doi.org/10.1107/S1600536809041609 Text en © Kavitha et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kavitha, T.
Sakthivel, P.
Ponnuswamy, S.
Ilango, S. S.
Ponnuswamy, M. N.
1-Formyl-r-2,c-6-bis­(4-methoxy­phen­yl)-t-3,t-5-dimethyl­piperidin-4-one
title 1-Formyl-r-2,c-6-bis­(4-methoxy­phen­yl)-t-3,t-5-dimethyl­piperidin-4-one
title_full 1-Formyl-r-2,c-6-bis­(4-methoxy­phen­yl)-t-3,t-5-dimethyl­piperidin-4-one
title_fullStr 1-Formyl-r-2,c-6-bis­(4-methoxy­phen­yl)-t-3,t-5-dimethyl­piperidin-4-one
title_full_unstemmed 1-Formyl-r-2,c-6-bis­(4-methoxy­phen­yl)-t-3,t-5-dimethyl­piperidin-4-one
title_short 1-Formyl-r-2,c-6-bis­(4-methoxy­phen­yl)-t-3,t-5-dimethyl­piperidin-4-one
title_sort 1-formyl-r-2,c-6-bis­(4-methoxy­phen­yl)-t-3,t-5-dimethyl­piperidin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971115/
https://www.ncbi.nlm.nih.gov/pubmed/21578409
http://dx.doi.org/10.1107/S1600536809041609
work_keys_str_mv AT kavithat 1formylr2c6bis4methoxyphenylt3t5dimethylpiperidin4one
AT sakthivelp 1formylr2c6bis4methoxyphenylt3t5dimethylpiperidin4one
AT ponnuswamys 1formylr2c6bis4methoxyphenylt3t5dimethylpiperidin4one
AT ilangoss 1formylr2c6bis4methoxyphenylt3t5dimethylpiperidin4one
AT ponnuswamymn 1formylr2c6bis4methoxyphenylt3t5dimethylpiperidin4one

Ejemplares similares