Bis(dimethyl sulfoxide-κO)bis­(mercapto­acetato-κ(2) O,S)tin(IV)

In the title compound, [Sn(C(2)H(2)O(2)S)(2)(C(2)H(6)OS)(2)], the mercaptoacetato ligands chelate to Sn(IV) through S and one O atoms. The metal centre is also coordinated by two dimethyl sulfoxide (DMSO) ligands through the O atom, leading to an overall distorted octahedral coordination environment...

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Detalles Bibliográficos
Autor principal: Song, Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971123/
https://www.ncbi.nlm.nih.gov/pubmed/21578179
http://dx.doi.org/10.1107/S160053680904361X
Descripción
Sumario:In the title compound, [Sn(C(2)H(2)O(2)S)(2)(C(2)H(6)OS)(2)], the mercaptoacetato ligands chelate to Sn(IV) through S and one O atoms. The metal centre is also coordinated by two dimethyl sulfoxide (DMSO) ligands through the O atom, leading to an overall distorted octahedral coordination environment for the Sn(IV) atom. The mol­ecular adduct lies on a twofold rotation axis.

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