Piperazine-1,4-diium bis­[tetra­chlorido­aurate(III)] dihydrate

In the title compound, (C(4)H(12)N(2))[AuCl(4)](2)·2H(2)O, the Au(III) atom has a square-planar geometry. The piperazinium dication lies on an inversion centre and adopts a typical chair conformation. In the crystal, a combination of N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds results in the formation o...

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Detalles Bibliográficos
Autores principales: Polishchuk, Anna V., Karaseva, Emilia T., Pushilin, Mikhail A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971124/
https://www.ncbi.nlm.nih.gov/pubmed/21578127
http://dx.doi.org/10.1107/S1600536809041063
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author Polishchuk, Anna V.
Karaseva, Emilia T.
Pushilin, Mikhail A.
author_facet Polishchuk, Anna V.
Karaseva, Emilia T.
Pushilin, Mikhail A.
author_sort Polishchuk, Anna V.
collection PubMed
description In the title compound, (C(4)H(12)N(2))[AuCl(4)](2)·2H(2)O, the Au(III) atom has a square-planar geometry. The piperazinium dication lies on an inversion centre and adopts a typical chair conformation. In the crystal, a combination of N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds results in the formation of a three-dimensional network.
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spelling pubmed-29711242010-12-30 Piperazine-1,4-diium bis­[tetra­chlorido­aurate(III)] dihydrate Polishchuk, Anna V. Karaseva, Emilia T. Pushilin, Mikhail A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(4)H(12)N(2))[AuCl(4)](2)·2H(2)O, the Au(III) atom has a square-planar geometry. The piperazinium dication lies on an inversion centre and adopts a typical chair conformation. In the crystal, a combination of N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds results in the formation of a three-dimensional network. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971124/ /pubmed/21578127 http://dx.doi.org/10.1107/S1600536809041063 Text en © Polishchuk et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Polishchuk, Anna V.
Karaseva, Emilia T.
Pushilin, Mikhail A.
Piperazine-1,4-diium bis­[tetra­chlorido­aurate(III)] dihydrate
title Piperazine-1,4-diium bis­[tetra­chlorido­aurate(III)] dihydrate
title_full Piperazine-1,4-diium bis­[tetra­chlorido­aurate(III)] dihydrate
title_fullStr Piperazine-1,4-diium bis­[tetra­chlorido­aurate(III)] dihydrate
title_full_unstemmed Piperazine-1,4-diium bis­[tetra­chlorido­aurate(III)] dihydrate
title_short Piperazine-1,4-diium bis­[tetra­chlorido­aurate(III)] dihydrate
title_sort piperazine-1,4-diium bis­[tetra­chlorido­aurate(iii)] dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971124/
https://www.ncbi.nlm.nih.gov/pubmed/21578127
http://dx.doi.org/10.1107/S1600536809041063
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AT pushilinmikhaila piperazine14diiumbistetrachloridoaurateiiidihydrate

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